| Texto completo | |
| Autor(es): |
Rodrigues, Everton Augusto
;
Violin, Daniel Silva
;
Mastelaro, Valmor Roberto
;
Neves, Tauany de Figueiredo
;
Prediger, Patricia
Número total de Autores: 5
|
| Tipo de documento: | Artigo Científico |
| Fonte: | International Journal of Biological Macromolecules; v. 256, p. 15-pg., 2023-12-01. |
| Resumo | |
Polymer-based membranes containing nanocellulose and natural macromolecules have potential to treat water, however few works have associated the changes in chemical and morphological membrane's features with their performance as adsorbent. Herein, a new green composite based on nanocellulose (NC) and alkylated tannic acid (ATA) and cross-linked with proanthocyanidin was produced and incorporated into polyacrylonitrile (PAN) membranes to eliminate propranolol (PRO) from water. Characterizations revealed that the increasing of NCATA content reduced the pore size of the membrane's upper surface and made the finger like structure of the sublayer disappear, due to the formation of hydrophilic domains of NC/ATA which speeds up the external solidification step. The presence of NC-ATA reduced the hydrophilicity, from a water contact angle of 3.65 degrees to 16.51 degrees, the membrane roughness, from 223.5 to 52.0 nm, and the zeta potential from -25.35 to -55.20 mV, improving its features to be a suitable adsorbent of organic molecules. The membranes proved to be excellent green adsorbent, tridimensional, and easy to remove after use, and qmax for PRO was 303 mg center dot g- 1. The adsorption mechanism indicates that H-bonds, ion exchange, and 7C-7C play important role in adsorption. NC-ATA@PAN kept high removal efficiencies after four cycles, evidencing the potential for water purification. (AU) | |
| Processo FAPESP: | 13/07296-2 - CDMF - Centro de Desenvolvimento de Materiais Funcionais |
| Beneficiário: | Elson Longo da Silva |
| Modalidade de apoio: | Auxílio à Pesquisa - Centros de Pesquisa, Inovação e Difusão - CEPIDs |
| Processo FAPESP: | 22/14834-0 - Síntese de novos nanoadsorventes através de protocolos verdes e suas aplicações na remoção de poluentes em águas |
| Beneficiário: | Patricia Prediger |
| Modalidade de apoio: | Auxílio à Pesquisa - Regular |
| Processo FAPESP: | 19/25228-0 - Desenvolvimento de novas membranas baseadas em óxido de grafeno para a remoção de contaminantes em água |
| Beneficiário: | Tauany de Figueiredo Neves |
| Modalidade de apoio: | Bolsas no Brasil - Doutorado Direto |