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Synthesis and Magnetic Characterization of Dispersed FexNi100-x (x=10, 20, 30, 40, and 50) Nanoalloys Using the Thermal Decomposition Method

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Autor(es):
Peixoto, E. B. ; Andrade, L. F. S. ; Carvalho, M. H. ; Santos, J. D. T. ; Silva, L. S. ; Duque, J. G. S.
Número total de Autores: 6
Tipo de documento: Artigo Científico
Fonte: Brazilian Journal of Physics; v. 55, n. 1, p. 7-pg., 2025-02-01.
Resumo

In this paper, we report on synthesis and magnetic properties of dispersed FexNi1-x (x = 10, 20, 30, 40, and 50) nanoalloys grown by thermal decomposition. X-ray diffraction patterns show that the majority crystalline phase is consistent with a fcc crystal structure (space group Fm3m) for all samples. Magnetization as a function of magnetic field and temperature shows that FexNi1-x are superparamagnetic with blocking temperatures around 10 K. However, for all samples, it is possible to observe a second very broad maximum, which can be ascribed to a bimodal nanoparticle size distribution and/or Ni nanoparticles for the case of samples grown with x = 10, 20, and 30. Finally, we argue that the nanoalloy size distribution and/or interaction effects should play a crucial role in determining the magnetic behavior of samples once we are not able to fit our HC(T) data using the Neel relaxation and the Bean-Livingston approaches in a wide temperature range. (AU)

Processo FAPESP: 20/10580-8 - Síntese e caracterização de nanofios de férmions pesados supercondutores da família CeMnIn3n+2 (M = Co, Rh, In; n = 0,1)
Beneficiário:Maria Helena Carvalho da Costa
Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado