| Texto completo | |
| Autor(es): |
Beraldo, Cleiton S.
;
Follegatti-Romero, Luis A.
;
Kontogeorgis, Georgios M.
;
Liang, Xiaodong
Número total de Autores: 4
|
| Tipo de documento: | Artigo Científico |
| Fonte: | Fluid Phase Equilibria; v. 598, p. 14-pg., 2025-11-01. |
| Resumo | |
This study presents the first comparison of SAFT-VR Mie and PC-SAFT in modeling CO2 solubility in Deep Eutectic Solvents (DESs). Experimental density data was used to adjust pure-component parameters (m, sigma, and epsilon) for DESs in the SAFT models, whereas the unlike-segment interaction energy between CO2 and the DES was either calculated with combining rules or optimized to reproduce experimental solubility data. A simplified Hudson-McCoubrey combining rule (ionization potentials assumed equal), applied for the first time to CO2-DES systems, was compared with the conventional Lorentz-Berthelot rule. Four hydrophilic and six hydrophobic DESs were modeled as pseudo-pure components, either as non-associating or associating species, following 2B or 4C association schemes in both equations of state. It was found that the Lorentz-Berthelot rule is unsuitable for CO2-DES phase equilibrium modeling, particularly for hydrophobic DESs, while the Hudson-McCoubrey rule provided excellent agreement with experimental data for both SAFT-VR Mie and PC-SAFT, performing comparably to models with unlike-segment interaction energy obtained empirically. The 2B and 4C association schemes produced accurate solubility predictions and demonstrated slightly superior performance compared to the inert approach, particularly in the case of hydrophobic DESs. Additionally, CO2 was modeled as either a neutral component or with 2B cross-association with DES, showing no significant difference in results. Finally, Helmholtz energy contributions to the residual pressure of pure hydrophobic DESs were analyzed, revealing that while association effects were minor, they positively influenced CO2 solubility predictions. (AU) | |
| Processo FAPESP: | 24/10537-6 - Prh06.1 - engenharia com ênfase em petróleo da escola politécnica da usp |
| Beneficiário: | Marcelo Ramos Martins |
| Modalidade de apoio: | Auxílio à Pesquisa - Regular |
| Processo FAPESP: | 19/22085-4 - Equilíbrio líquido-líquido na recuperação de ácidos carboxílicos de águas residuárias usando solventes verdes |
| Beneficiário: | Luis Alberto Follegatti Romero |
| Modalidade de apoio: | Auxílio à Pesquisa - Regular |