Grain boundary phenomena at barium titanate doped by vapour phase diffusion

• Processo: 01/02560-6
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado
• Data de Início da vigência: 01 de julho de 2001
• Data de Término da vigência: 31 de janeiro de 2002
• Área de conhecimento: Engenharias - Engenharia de Materiais e Metalúrgica - Materiais Não-metálicos
• Pesquisador responsável: José Arana Varela
• Beneficiário: Suman Chatterjee
• Instituição Sede: Instituto de Química (IQ). Universidade Estadual Paulista (UNESP). Campus de Araraquara. Araraquara , SP, Brasil
• Vinculado ao auxílio: 00/01991-0 - Síntese e caracterização de filmes finos e cerâmicas ferroelétricos, AP.TEM
• Assunto(s): Titanatos Cerâmica (materiais cerâmicos)
• Palavra(s)-Chave do Pesquisador: Barium Titanate | Doping | Grain Boundary | Semiconduction | Vapour Phase Diffusion

Resumo

In a variety of ceramic processes, doping in trace amounts is required e.g., to achieve semiconduction, to control grain size, to control the grain boundary potential barrier, etc. Besides, a preferential distribution of dopants in grains and grain boundaries is also very important in various device fabrications. Hence, this grain boundary engineering is a very important topic of concern now a day in the electroceramic industry. The grain boundary plays a vital role in various electroceramic components like - PTC thermistors, Varistors, Barrier layer capacitors, etc. The composition, structure and phases in the grain boundary are controlled by the variation of sintering temperature, cooling rate, addition of second phase in the grain boundary, addition of dopants and various other mechanisms. The main objective of this project is to develop a simple, cost-effective and useful method for grain boundary engineering by doping through vapour phase. After realization, the method can make use of highly developed technology of semiconductor doping with a higher degree of accuracy compared to solid state doping conventionally used in ceramic industry. (AU)