| Texto completo | |
| Autor(es): |
Ap Christinelli, Wania
;
Trench, Aline B.
;
Pereira, Ernesto C.
Número total de Autores: 3
|
| Tipo de documento: | Artigo Científico |
| Fonte: | SOLAR ENERGY MATERIALS AND SOLAR CELLS; v. 157, p. 703-708, DEC 2016. |
| Citações Web of Science: | 8 |
| Resumo | |
In this work, a new material was developed to be used as the active electrode in an electrochromic device based on layer-by-layer poly(o-methoxyaniline) and poly(3-thiopheneacetic acid) films. Its properties were compared to a poly(o-methoxyaniline) film prepared by casting with similar electrochemical properties. The film preparation technique, layer-by-layer, guarantees molecular interaction between layers. In this case, the interaction leads to a self-doping effect, inhibiting the ion transport from the solution to the polymer which is the rate limiting step during the device operation. The results show both a decrease in the time constant for color change as well as a strong increase in the coloration efficiency, from 144.7 to 542 cm(2) C-1 for POMA casting and LBL films, respectively. (C) 2016 Elsevier B.V. All rights reserved. (AU) | |
| Processo FAPESP: | 13/07296-2 - CDMF - Centro de Desenvolvimento de Materiais Funcionais |
| Beneficiário: | Elson Longo da Silva |
| Modalidade de apoio: | Auxílio à Pesquisa - Centros de Pesquisa, Inovação e Difusão - CEPIDs |
| Processo FAPESP: | 11/10897-2 - Caracterização dos processos redox e do envelhecimento eletroquímico de filmes automontados de polímeros condutores |
| Beneficiário: | Wania Aparecida Christinelli |
| Modalidade de apoio: | Bolsas no Brasil - Doutorado Direto |