Structure of P2O5-SiO2 Pure Network Former Glasses Studied by Solid State NMR Spectroscopy

Autor(es)

de Oliveira, Jr., Marcos ^[1] ; Aitken, Bruce ^[2] ; Eckert, Hellmut ^{[1, 3]}

Afiliação do(s) autor(es)

^[1] Univ Sao Paulo, Inst Fis Sao Carlos, CP 369, BR-13566590 Sao Carlos, SP - Brazil

^[2] Corning Inc, Corning, NY 14831 - USA

^[3] Westfalische Wilhelms Univ Munster, Inst Phys Chem, Corrensstr 30, D-48149 Munster - Germany

• Tipo de documento: Artigo Científico
• Fonte: Journal of Physical Chemistry C; v. 122, n. 34, p. 19807-19815, AUG 30 2018.
• Citações Web of Science: 2

Resumo

The structure of binary (SiO2)(100-x)-(P2O5)(x) glasses has been investigated by Raman scattering, Si-29 and P-31 magic angle spinning (MAS) as well as static P-31 NMR spectroscopy. Si-29 chemical shift trends reflect the successive replacement of Si-O-Si by Si-O-P linkages as the compositional parameter x is increased. While P-31 MAS NMR does not resolve separate phosphate species, the static P-31 NMR lineshapes were successfully simulated by considering the effect of uncorrelated distribution functions of the chemical shift tensor components upon the line shape. On the basis of these simulations, which were also found to be consistent with the experimental P-31 MAS NMR spectra, two distinct sites can be resolved: a dominant site characterized by an axially symmetric chemical shift tensor, assigned to P-(3) units, and (only in the case of the x = 25 and 30 glasses) a Gaussian component reflecting phosphate species interacting with five- and six-coordinated silicon species. For 0 <= x <= 25, the decrease in average coordination number may provide the structural explanation for the strong decrease in the glass transition and liquidus temperatures over this composition range, whereas the subsequent increase in T-g at higher P2O5 contents is correlated with the appearance of the higher-coordinated silicon species. While these higher-coordinated silicon species occur within separate microdomains, P-31 spin echo decay spectroscopy suggests that the majority of P atoms tend to be randomly distributed in space, consistent with a statistical P-O-P, Si-O-P, and Si-O-Si connectivity distribution. (AU)

• Processo FAPESP: 13/07793-6 - CEPIV - Centro de Ensino, Pesquisa e Inovação em Vidros
• Beneficiário: Edgar Dutra Zanotto
• Modalidade de apoio: Auxílio à Pesquisa - Centros de Pesquisa, Inovação e Difusão - CEPIDs
• Processo FAPESP: 13/23490-3 - Técnicas de ressonância magnética empregadas no estudo da correlação estrutura/propriedades em vidros e vitrocerâmicas fotônicos
• Beneficiário: Marcos de Oliveira Junior
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado