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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Production and Corrosion Resistance of Thermally Sprayed Fe-Based Amorphous Coatings from Mechanically Milled Feedstock Powders

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Autor(es):
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Koga, Guilherme Y. [1, 2] ; Jorge, Jr., Alberto M. [1, 2] ; Roche, Virginie [2] ; Nogueira, Ricardo P. [3, 2] ; Schulz, Robert [4] ; Savoie, Sylvio [4] ; Melle, Ana K. [1] ; Loable, Carole [2] ; Bolfarini, Claudemiro [1] ; Kiminami, Claudio S. [1] ; Botta, Walter J. [1]
Número total de Autores: 11
Afiliação do(s) autor(es):
[1] Univ Fed Sao Carlos, Dept Engn Mat, Rod Washington Luis, Km 235, BR-13565905 Sao Carlos, SP - Brazil
[2] Grenoble Alpes Univ, CNRS, LEPMI, F-38000 Grenoble - France
[3] Khalifa Univ Sci & Technol, Gas Res Ctr, Abu Dhabi - U Arab Emirates
[4] Hydroquebec Res Inst, 1800 Boul Lionel Boulet, Varennes, PQ J3X 1S1 - Canada
Número total de Afiliações: 4
Tipo de documento: Artigo Científico
Fonte: METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE; v. 49A, n. 10, p. 4860-4870, OCT 2018.
Citações Web of Science: 6
Resumo

Mechanically milled FeCrNbB feedstock powders from commercial precursors were used to produce amorphous coatings through two different industrial thermal-spraying techniques: high-velocity oxygen fuel (HVOF) and flame spraying. Microstructure, thermal behavior, and hardness of the coatings and their corrosion resistances in acidic and alkaline chloride-rich media were comparatively studied. HVOF process was effective to produce similar to 200-mu m-thick highly amorphous coatings with hardness over than 700 HV(0.3 )and low porosity (similar to 5 pct). Flame-sprayed similar to 220-mu m-thick coatings were nanocrystalline, composed of alpha-Fe, Fe2B, FeNbB, and Fe2O3 phases and presented hardness of 564 HV0.3 and similar to 10 pct porosity. Electrochemical measurements indicated that HVOF coatings exhibit higher corrosion resistance than flame-sprayed ones thanks to the higher amorphous content and lower porosity resulting from the former processing route. Electrochemical impedance spectroscopy results demonstrated that amorphous HVOF Fe60Cr8Nb8B24 (at. pct) coatings are interesting to protect mild steels such as the API 5L X80 against corrosion in chloride-rich environments. (C) The Minerals, Metals \& Materials Society and ASM International 2018 (AU)

Processo FAPESP: 13/05987-8 - Processamento e caracterização de ligas metálicas amorfas, metaestáveis e nano-estruturadas
Beneficiário:Claudio Shyinti Kiminami
Linha de fomento: Auxílio à Pesquisa - Temático
Processo FAPESP: 17/09237-4 - Design e produção de aços inoxidáveis modificados com boro conformados por spray de elevada resistência a corrosão e ao desgaste
Beneficiário:Guilherme Yuuki Koga
Linha de fomento: Bolsas no Brasil - Pós-Doutorado