REVERSIBILITY OF AL-KAOLIN AND AL-HUMIC AGGREGATES MONITORED BY STABLE DIAMETER AND SIZE DISTRIBUTION

Autor(es)

Moruzzi, Rodrigo Braga ^[1] ; Grava da Silva, Pedro Augusto ^[1]

Afiliação do(s) autor(es)

^[1] Univ Estadual Paulista Unesp, Inst Geociencias & Ciencias Exatas, Ave 24-A, 1515, CP 178, BR-13506900 Rio Claro, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Brazilian Journal of Chemical Engineering; v. 35, n. 3, p. 1029-1037, JUL-SEP 2018.
• Citações Web of Science: 1

Resumo

Abstract The reversibility of aggregates during flocculation was investigated. The stable diameter (d) and the power law slope coefficient of the particle size distribution (β) were applied to follow re-formation after breakage. A non-intrusive image-based technique was used for monitoring flocs. Aggregates were formed by adding alum [Al2(SO4)3·18H2O] by the sweep-coagulation mechanism to two synthetic waters, prepared from kaolin (Fluka) and humic acid (Aldrich Chemical). Velocity gradients (G) varied from 20 to 120 s-1 during experiments, and the rupture occurred under controlled conditions. After rupture, the initial condition was reinstated and reversibility analyzed. Results pointed out the irreversibility of breakage for both Al-kaolin and Al-humic flocs. The stable diameter of aggregates after breakage (d2) varied from 157 to 132 µm for Al-humic and from 233 to 123µm for Al-kaolin aggregates, using G from 20 to 120 s-1. β 2 values varied from 1.2 to 4.6 for Al-humic and from 0.6 to 7.7 for Al-kaolin. (AU)

• Processo FAPESP: 13/25641-9 - Determinação dos procedimentos para aquisição de imagem visando à determinação de tamanho de partículas floculentas em reatores estáticos
• Beneficiário: Pedro Augusto Grava da Silva
• Modalidade de apoio: Bolsas no Brasil - Iniciação Científica