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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Soil analytical quality control by traditional and spectroscopy techniques: Constructing the future of a hybrid laboratory for low environmental impact

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Autor(es):
Dematte, Jose Alexandre M. [1] ; Dotto, Andre Carnieletto [1] ; Bedin, Luis Gustavo [1] ; Sayao, Veridiana Maria [1] ; Barros e Souza, Arnaldo [1]
Número total de Autores: 5
Afiliação do(s) autor(es):
[1] Univ Sao Paulo, Coll Agr Luiz de Queiroz ESALQ, Dept Soil Sci, Av Padua Dias 11, BR-13418260 Piracicaba, SP - Brazil
Número total de Afiliações: 1
Tipo de documento: Artigo Científico
Fonte: Geoderma; v. 337, p. 111-121, MAR 1 2019.
Citações Web of Science: 5
Resumo

Soil analysis is an important information in agriculture and environmental monitoring. It is usually performed by wet chemical analysis with high cost and chemical products consumption. In the world, it is estimated that 1.5 billion ha is used as agricultural area. If every 5 ha 2 samples (2 depths) were collected, we would have 600 million soil samples for chemical and granulometric analysis. Considering just the analysis of organic matter (OM) by wet combustion method in the laboratory as an example, we would be utilizing about 840 thousand kg of dichromate and ammonium ferrous sulfate and 3 million L of sulfuric acid. The use of these reagents can have a huge ecological consequence if they do not have an adequate final disposal. An alternative methodology such as proximal sensing can be utilized with low environmental impact. Therefore, the objective of this study was to: i) evaluate the analytical quality of soil attributes via different traditional laboratories and sensors, ii) evaluate the prediction of the models using sensors, iii) assess the uncertainties of lime recommendation analyzed by the laboratories. We applied 96 soil samples at two depths collected in Sao Paulo State, Brazil. The determination of 15 soil attributes was performed by four different routine laboratories, and they were predicted by 4 sensors (400-2500 nm). Results indicate that the determination of attributes via chemical analysis with low quality led to high error in spectral models. The great predictive performances of clay, OM, cation exchange capacity (CEC), and pH enable the use of sensors in the evaluation of these attributes. Overall, the criteria for classification of analytical results showed that sand, silt, clay, pH, OM, CEC, and base saturation were the attributes that can be determined by the spectroscopy technique with high-quality outcome. The lime recommendation derived from proximal sensor analysis can be used as an efficient method, since it presented a high correlation with the laboratory result. In this sense, a hybrid laboratory analysis can be developed to optimize analysis with better quality control, which is indicated as a great opportunity in the near future. (AU)

Processo FAPESP: 14/22262-0 - Geotecnologias no mapeamento digital pedológico detalhado e biblioteca espectral de solos do Brasil: desenvolvimento e aplicações
Beneficiário:José Alexandre Melo Demattê
Modalidade de apoio: Auxílio à Pesquisa - Temático
Processo FAPESP: 17/03207-6 - Geotecnologias no mapeamento digital pedológico detalhado e biblioteca espectral de solos do Brasil: desenvolvimento e aplicações
Beneficiário:Andre Carnieletto Dotto
Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado