Fabrication and electrochemical evaluation of micro-supercapacitors prepared by direct laser writing on free-standing graphite oxide paper

Autor(es)

Kumar, Rajesh ^[1] ; Joanni, Ednan ^[2] ; Savu, Raluca ^[3] ; Pereira, Matheus S. ^[4] ; Singh, Rajesh K. ^[5] ; Constantino, Carlos J. L. ^[4] ; Kubota, Lauro T. ^[6] ; Matsuda, Atsunori ^[1] ; Moshkalev, Stanislav A. ^[3]

Afiliação do(s) autor(es)

^[1] Toyohashi Univ Technol, Dept Elect & Elect Informat Engn, 1-1 Hibarigaoka, Tempaku Cho, Toyohashi, Aichi 4418580 - Japan

^[2] Ctr Informat Technol Renato Archer CTI, BR-13069901 Campinas, SP - Brazil

^[3] Univ Campinas UNICAMP, Ctr Semicond Components & Nanotechnol CCS Nano, BR-13083870 Campinas, SP - Brazil

^[4] Sao Paulo State Univ, Dept Phys, Fac Sci & Technol, BR-19060900 Presidente Prudente, SP - Brazil

^[5] CUHP, Sch Phys & Mat Sci, Dharamshala 176215, HP - India

^[6] Univ Campinas UNICAMP, Inst Chem, Dept Analyt Chem, POB 6154, BR-13084974 Campinas, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: ENERGY; v. 179, p. 676-684, JUL 15 2019.
• Citações Web of Science: 4

Resumo

This article presents results of a pulsed UV laser method for the simultaneous reduction of graphite oxide (GO) and patterning of reduced graphene oxide (rGO). This direct laser writing method was applied to the fabrication of graphene-based, in-plane interdigitated micro-supercapacitors (mu-SCs), prepared on free-standing GO paper (10 mu m thick). The electrochemical performance of mu-SCs was studied using two different electrolytes (KOH and NaCl). The results from cyclic voltammetry measurements exhibited typical electrical double layer behavior, with specific capacitances of 9.3 mu F/cm(2) and 13.8 mu F/cm(2) (at a scan rate of 10 mV/s) for KOH and NaCl electrolytes, respectively. The mu-SCs exhibited good performance, with retention of 95% of the original capacitance values after 3400 charge-discharge cycles. When compared to devices obtained by conventional lithographic techniques, the laser fabrication of planar mu-SCs is faster, cost-effective and scalable. We believe this one-step and environmentally friendly laser-assisted method to be a good alternative for the fabrication of flexible energy storage devices. (C) 2019 Elsevier Ltd. All rights reserved. (AU)

• Processo FAPESP: 17/22186-0 - Efeito e formato de nanoparticulas metálicas na sua interação com biomoléculas e/ou vesículas gigantes de fosfolipidios
• Beneficiário: Rajesh Kumar
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado
• Processo FAPESP: 13/14262-7 - Filmes nanoestruturados de materiais de interesse biológico
• Beneficiário: Osvaldo Novais de Oliveira Junior
• Modalidade de apoio: Auxílio à Pesquisa - Temático