Nickel pyrophosphate combined with graphene nanoribbon used as efficient catalyst for OER

Autor(es)

Souza, Alan S. ^[1] ; Bezerra, Leticia S. ^[1] ; Cardoso, Eduardo S. F. ^[1] ; Fortunato, Guilherme V. ^{[2, 1]} ; Maia, Gilberto ^[1]

Afiliação do(s) autor(es)

^[1] Univ Fed Mato Grosso do Sul, Inst Chem, Ave Senador Filinto Muller 1555, BR-79074460 Campo Grande, MS - Brazil

^[2] Univ Sao Paulo, Inst Chem Sao Carlos, Ave Trabalhador Sao Carlense 400, BR-13566590 Sao Carlos, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: JOURNAL OF MATERIALS CHEMISTRY A; v. 9, n. 18, p. 11255-11267, MAY 14 2021.
• Citações Web of Science: 0

Resumo

Although noble-metal based materials (IrO2 and RuO2) are regarded state-of-the-art catalysts for oxygen evolution reaction (OER), their high price, long-term instability, and scarcity have fueled the search for alternative materials that are relatively cheaper and highly abundant in nature and which can be used for the development of electrolyzers that are suitable for hydrogen production. The present work reports the development and application of a new hybrid catalyst derived from the thermal treatment of a mixture of graphene nanoribbons (GNR) and nickel pyrophosphate (beta-Ni2P2O7); the proposed hybrid material was found to present remarkably improved properties which include easy charge transfer, high electroactive surface area, high activity, and effective resistance to corrosion in OER in alkaline medium. The combination of highly dispersed beta-Ni2P2O7-30 wt% in direct contact with GNR-70 wt%, coupled with the application of thermal treatment - which ensured some enrichment of Ni in the GNiPy350N catalyst, contributed toward the production of an efficient material with excellent and stable OER activity in alkaline conditions. Compared to the state-of-the-art IrO2 (300 mV), the GNiPy350N catalyst required an overpotential of approximately 320 mV to reach the current density of 10 mA cm(-2) when immobilized on carbon paper electrode. (AU)

• Processo FAPESP: 19/04421-7 - Produção e caracterização de nanocompositos metal-grafeno ou óxido de grafeno visando a produção eletrocatalítica de peróxido de hidrogênio: Uma aplicação à degradação de desreguladores endócrinos por processos eletroquímicos oxidativos avançados
• Beneficiário: Guilherme Vilalba Fortunato
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado