Antisolvent versus ultrasonication: Bottom-up and top-down approaches to produce lignin nanoparticles (LNPs) with tailored properties

Autor(es)

Camargos, Camilla H. M. ^[1] ; Rezende, Camila A. ^[1]

Afiliação do(s) autor(es)

^[1] Univ Campinas UNICAMP, Inst Chem, Phys Chem Dept, POB 6154, BR-13083970 Campinas, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: International Journal of Biological Macromolecules; v. 193, n. A, p. 647-660, DEC 15 2021.
• Citações Web of Science: 0

Resumo

In spite of the increasing amount of literature on the production and application of lignin nanoparticles (LNPs), little or no attention has been paid so far to the influence of different production methods on the properties of these nanostructures. Herein, we propose a comprehensive study to assess the impact of several factors on the color, morphology, colloidal stability, antioxidant capacity, and UV-shielding performance of LNPs. LNPs were obtained by two different routes: a bottom-up approach based on the self-assembly in a solvent-antisolvent system with acetone/lignin/water; or a top-down approach based on the ultrasonication of never-dried lignin aqueous suspensions. The starting lignin was extracted from elephant grass leaves or stems, so that the influence of anatomical origin and molecular weight could also be investigated. Moreover, lignin was oxidized prior to being converted into LNPs, allowing for comparisons between different oxidation degrees. This study showed that interesting properties of LNPs can be easily tailored and combined focusing on the various applications of these versatile nanostructures. In a model application, different types of LNPs were incorporated into poly(vinyl alcohol)-based nanocomposites, modulating the UV-protection capability of the polymer matrix. (AU)

• Processo FAPESP: 18/23769-1 - Obtenção e aplicações de nanoestruturas provenientes de biomassa vegetal
• Beneficiário: Camila Alves de Rezende
• Modalidade de apoio: Auxílio à Pesquisa - Regular