Freestanding niobium pentoxide-decorated multiwalled carbon nanotube electrode: Charge storage mechanism in sodium-ion pseudocapacitor and battery

Autor(es)

Real, Carla G. ; Thaines, Ericson H. N. S. ; Pocrifka, Leandro A. ; Freitas, Renato G. ; Singh, Gurpreet ; Zanin, Hudson

• Tipo de documento: Artigo Científico
• Fonte: JOURNAL OF ENERGY STORAGE; v. 52, p. 16-pg., 2022-05-18.

Resumo

This study investigated flexible, freestanding niobium pentoxide (Nb2O5) decorated multiwalled carbon nano tube (MWCNT) electrode material in a sodium-ion pseudocapacitor and its respective energy storage mechanism. Sodium is an abundant element in the Earth's crust, with attractive sustainability and low-cost appeal for the scientific community and energy markets such as electric vehicles and renewable energies. Combined with niobium pentoxide and carbon nanotubes, sodium ions can perform ultra-fast intercalation into niobium pent oxide and electrostatic adsorption onto carbon high surface areas. Niobium pentoxide particles were investigated using X-ray diffraction via Rietveld refinement, a powerful technique to study crystalline materials' electronic and structural properties that directly influence Na+-ion diffusion. The niobium pentoxide-decorated MWCNT electrode material was investigated within a symmetric supercapacitor (SIC) and as an anode for sodium-ion batteries (SIBs). A finite-length transmission line was used to model the impedance behavior of the solid and liquid phases that comprised the material/solution interface. This numerical modelling allowed investigators to infer the presence of MWCNT as a nanostructured matrix since Nb2O5 dispersive nanoparticles increased the overall pseudopacacitance by 63.2% for Nb2O5/MWCNT compared to MWCNT nanostructured electrodes. Electrochemical findings revealed a maximum capacitance of 192 F g(-1) for the SIC full cell, with capacitance retention of 96% after 10,000 cycles. In addition, the SIC delivered outstanding power density from 98.7 to 24,671 W kg(-1) and high energy density from 5.4 to 2.7 W h kg(-1). In an SIB half-cell configuration, the electrode delivered a reversible sodium-ion storage capacity of ~163 mA h g(-1), with a retention capacity of ~68 mA h g(-1) after 100 cycles at 25 mA g(-1). These systems bridge the gap between supercapacitors and batteries by employing the best properties of them both. (AU)

• Processo FAPESP: 17/11958-1 - CINE - Divisão para Armazenamento de Energia Avançado
• Beneficiário: Rubens Maciel Filho
• Modalidade de apoio: Auxílio à Pesquisa - Programa Centros de Pesquisa em Engenharia
• Processo FAPESP: 14/02163-7 - Desenvolvimento de dispositivos supercapacitores a partir de grafenos, nanotubos de carbono e diamantes
• Beneficiário: Hudson Giovani Zanin
• Modalidade de apoio: Auxílio à Pesquisa - Jovens Pesquisadores