| Texto completo | |
| Autor(es): |
da Silva, Rodrigo Borges
;
Coelho, Felipe Lange
;
Silva, Henrique de Castro
;
Germino, Jose Carlos
;
Zambon Atvars, Teresa Dib
;
Rodembusch, Fabiano Severo
;
Teixeira Alves Duarte, Luis Gustavo
;
Schneider, Paulo Henrique
Número total de Autores: 8
|
| Tipo de documento: | Artigo Científico |
| Fonte: | Journal of Fluorescence; v. N/A, p. 13-pg., 2023-08-05. |
| Resumo | |
In this study, we present the synthesis of benzimidazo[1,2-a] quinoline-based heterocycles bearing organosulfur and organoselenium moieties through transition-metal-free cascade reactions involving a sequential intermolecular aromatic nucleophilic substitution (SNAr). Both sulfur and selenium derivatives presented absorption maxima located around 355 nm related to spin and symmetry allowing electronic (1)p-p* transitions, and fluorescence emission at the violet-blue region (similar to 440 nm) with relatively large Stokes shift. The fluorescence quantum yields were slightly influenced by the chalcogen, with the sulfur derivatives presenting higher values than the selenium analogs. In this sense, the quantum yields for selenium derivatives can probably be affected by the intersystem crossing or even the photoinduced electron transfer process (PET). The compounds were successfully applied in all-solution-processed organic light-emitting diodes (OLEDs), where poly(9-vinylcarbazole) was employed as a dispersive matrix generating single-layer device cells. The obtained electroluminescence spectra are a sum of benzimidazo[1,2-a]quinolines and PVK singlet and/or triplet emissive states, according to their respective energy band gaps. The best diode rendered a luminance of 25.4 cd.m(-2) with CIE (0.17, 0.14) and current efficiency of 20.2 mcd.A(-1), a fivefold improvement in comparison to the PVK device that was explained by a 50-fold increase of charge-carriers electrical mobility. (AU) | |
| Processo FAPESP: | 13/16245-2 - Propriedades fotofísicas de filmes finos de polímeros conjugados |
| Beneficiário: | Teresa Dib Zambon Atvars |
| Modalidade de apoio: | Auxílio à Pesquisa - Regular |