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(+/-)-(4aR,5R,8S,8aR)-8-(tert-Butyl-dimethylsilyloxy)-2,5,8a-trimethyl-4a, 5,8,8a-tetrahydronaphthalene-1,4-dione

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Autor(es):
Delling, Felix N. ; Zukerman-Schpector, Julio ; Brocksom, Timothy J. ; Brocksom, Ursula ; Finelli, Fernanda G. ; Tiekink, Edward R. T.
Número total de Autores: 6
Tipo de documento: Artigo Científico
Fonte: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS; v. 69, p. 9-pg., 2013-03-01.
Resumo

In the title compound, C19H30O3Si, both rings adopt a half-boat conformation. Overall, the molecule approximates a Ushape as the cyclo-2-ene-1,4-dione and butyldimethylsilyloxy substituents lie to the same side of the central cyclohexene ring; the methyl substituent lies to the other side of the molecule. In the crystal, linear supramolecular chains along the b axis are sustained by C-H center dot center dot center dot O interactions. (AU)

Processo FAPESP: 11/13993-2 - Metodologias para a síntese de terpenos bioativos
Beneficiário:Timothy John Brocksom
Modalidade de apoio: Auxílio à Pesquisa - Regular