| Texto completo | |
| Autor(es): |
Perez, H.
;
Correa, R. S.
;
O'Reilly, B.
;
Plutin, A. M.
;
Silva, C. C. P.
;
Mascarenhas, Y. P.
Número total de Autores: 6
|
| Tipo de documento: | Artigo Científico |
| Fonte: | JOURNAL OF STRUCTURAL CHEMISTRY; v. 53, n. 5, p. 6-pg., 2012-09-01. |
| Resumo | |
The title compound [Ni(C20H15N2OS)(2)] is prepared by the reaction of metal acetate with the corresponding acylthiourea derivative. The complex is characterized by elemental analysis, IR, H-1 and C-13 NMR, and its structure is determined by single crystal X-ray diffraction. The Ni(II) ion is coordinated by the S and O atoms of two N-benzoyl-N',N'-diphenylthiourea ligands in a slightly distorted square-planar coordination geometry. The two O and two S atoms are mutually cis to each other. The substance crystallizes triclinic (P-1 space group) with cell dimensions a = 10.7262(9) , b = 12.938(3) , c = 14.2085(12) , alpha = 74.650(4)A degrees, beta = 78.398(4)A degrees, gamma = 68.200(5)A degrees, and two formula units in the unit cell. The structure is very close to the related N-(2-furoyl) Ni complex reported previously. (AU) | |
| Processo FAPESP: | 09/08131-1 - Complexos de rutênio com ligantes de interesse biológico: aspectos químicos, estruturais e avaliação de suas citotoxicidades em células tumorais |
| Beneficiário: | Rodrigo de Souza Corrêa |
| Modalidade de apoio: | Bolsas no Brasil - Doutorado |