Borohydride electrooxidation on Au and Pt electrodes

Autor(es)

Lima, Fabio H. B. ; Pasqualeti, Anielli M. ; Concha, M. Belen Molina ; Chatenet, Marian ; Ticianelli, Edson A.

• Tipo de documento: Artigo Científico
• Fonte: Electrochimica Acta; v. 84, p. 11-pg., 2012-12-01.

Resumo

Direct borohydride fuel cells (DBFCs) are attractive energy generators for powering portable electronic devices, mainly due to their high energy density and number of electrons per borohydride ion. However, the lack of a highly efficient electrocatalyst for the borohydride oxidation reaction limits the performance of these devices. The most commonly studied electrocatalysts for this reaction are composed of gold and platinum. Nevertheless, for these metals, the borohydride electrooxidation reaction mechanism (BOR) is not completely understood, and the total oxidation reaction, involving eight electrons per BH4- species, competes with parallel reactions, with a lower number of exchanged electrons and/or with heterogeneous chemical hydrolysis. Considering the above-mentioned issues, this work presents recent advances in the knowledge of the BOR pathways on polycrystalline (bulk) Au and Pt electrocatalysts. It presents the studies of the BOR reaction on Au and Pt electrodes using in situ Fourier Transform Infrared Spectroscopy (FUR), and on-line Differential Electrochemical Mass Spectrometry (DEMS). The spectroscopic and spectrometric data provided physical evidence of intermediate species and the formation of H-2 in the course of the BOR as a function of the electrode potential. These results enabled to advance in the knowledge about the BOR pathways on Au and Pt electrocatalysts. (C) 2012 Elsevier Ltd. All rights reserved. (AU)

• Processo FAPESP: 09/07629-6 - Eletrocatálise IV: aspectos fundamentais e aplicados dos processos eletrocatalíticos, bio-eletrocatálise e instabilidades cinéticas
• Beneficiário: Edson Antonio Ticianelli
• Modalidade de apoio: Auxílio à Pesquisa - Programa BIOEN - Temático
• Processo FAPESP: 11/03672-4 - Investigação da atividade de eletrocatalisadores nanoestruturados para a eletrooxidação de íons BH4- em eletrólito alcalino
• Beneficiário: Aniélli Martini Pasqualeti
• Modalidade de apoio: Bolsas no Brasil - Mestrado