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Fluorescent Carbon Dots for Improved Visualization of Latent Fingermarks after Cyanoacrylate Fuming

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Autor(es):
Martins, Guilherme ; Barros, Rodrigo Meneses ; de Sousa, Myllena Paula ; Frin, Karina P. M. ; de Souza, Marco Antonio ; Paterno, Leonardo Giordano
Número total de Autores: 6
Tipo de documento: Artigo Científico
Fonte: ACS APPLIED NANO MATERIALS; v. 7, n. 22, p. 9-pg., 2024-11-07.
Resumo

The use of spectroscopic methods to process fingermark evidence is a key procedure in forensic laboratories for identifying the perpetrator of a crime. However, latent fingermarks must first be developed. While metal powders and dyes are commonly used as chemical developers, recent studies have shown that nanomaterials may offer superior development performance and numerous advantages. Herein, we corroborate this viewpoint reporting the successful utilization of carbon quantum dots (C-dots) as a fluorescent developer for latent fingerprint deposited on aluminum substrates and previously treated with cyanoacrylate fuming. These C-dots exhibit strong blue luminescence driven by emission from both core and surface emissive sites. Owing to the hydrogen bonds established between -OH, -COOH, and -NH groups from C-dots and -C N and -COOR in polymerized cyanoacrylate, C-dots adhere strongly to fingermark ridges from various individuals, significantly enhancing contrast and details within pores and ridge morphology. The adsorbed C-dots are stable, and the photoluminescent mark remains visible even after washing the developed fingermarks with water. (AU)

Processo FAPESP: 13/07296-2 - CDMF - Centro de Desenvolvimento de Materiais Funcionais
Beneficiário:Elson Longo da Silva
Modalidade de apoio: Auxílio à Pesquisa - Centros de Pesquisa, Inovação e Difusão - CEPIDs
Processo FAPESP: 17/18063-0 - Avaliação de compostos luminescentes de Re(I) em bioimagem e/ou como agentes antitumorais
Beneficiário:Karina Passalacqua Morelli Frin
Modalidade de apoio: Auxílio à Pesquisa - Regular