| Texto completo | |
| Autor(es): |
Ferreira, P. N.
;
Lucrezi, R.
;
Guilhon, I.
;
Marques, M.
;
Teles, L. K.
;
Heil, C.
;
Eleno, L. T. F.
Número total de Autores: 7
|
| Tipo de documento: | Artigo Científico |
| Fonte: | MATERIALS TODAY PHYSICS; v. 48, p. 16-pg., 2024-09-10. |
| Resumo | |
Designing new, technologically relevant superconductors has long been at the forefront of solid-state physics and chemistry research. However, developing efficient approaches for modeling the thermodynamics of superconducting alloys while accurately evaluating their physical properties has proven to be a very challenging task. To fill this gap, we propose an ab initio thermodynamic statistical method, the Extended Generalized Quasichemical Approximation (EGQCA), to describe off-stoichiometric superconductors. Within EGQCA, one can predict any computationally accessible property of the alloy, such as the critical temperature in superconductors and the electron-phonon coupling parameter, as a function of composition and crystal growth conditions using a few small supercells. Importantly, EGQCA incorporates directly chemical ordering, lattice distortions, and vibrational contributions. As a proof of concept, we applied EGQCA to the well-known Al-doped MgBb(2) and to niobium alloyed with titanium and vanadium, showing a remarkable agreement with the experimental data. Additionally, we modeled the near-room temperature sodalite-like Y1-xCaxH6 superconducting solid solution, demonstrating that EGQCA particularly possesses a promising potential for designing in silico high-T-c superhydride alloys. Our approach enables the high-throughput screening of complex superconducting solid solutions, providing valuable insights into these systems' synthesis, thermodynamics, and physical properties. (AU) | |
| Processo FAPESP: | 20/08258-0 - Estudo ab initio de sistemas supercondutores e topológicos |
| Beneficiário: | Pedro Nunes Ferreira |
| Modalidade de apoio: | Bolsas no Brasil - Doutorado |
| Processo FAPESP: | 21/13441-1 - Algoritmos evolutivos ab initio na descoberta de novas fases em sistemas de teluretos de metais de transição sob pressão |
| Beneficiário: | Pedro Nunes Ferreira |
| Modalidade de apoio: | Bolsas no Exterior - Estágio de Pesquisa - Doutorado |