Macrosegregation of Impurities in Directionally Solidified Silicon

Autor(es)

Martorano, M. A. ^[1] ; Ferreira Neto, J. B. ^[2] ; Oliveira, T. S. ^{[1, 2]} ; Tsubaki, T. O.

Afiliação do(s) autor(es)

^[1] Univ Sao Paulo, Dept Met & Mat Engn, BR-05508900 Sao Paulo - Brazil

^[2] Inst Technol Res, Lab Met & Ceram Mat, BR-05508901 Sao Paulo - Brazil

• Tipo de documento: Artigo Científico
• Fonte: METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE; v. 42A, n. 7, p. 1870-1886, JUL 2011.
• Citações Web of Science: 18

Resumo

Directional solidification of molten metallurgical-grade Si was carried out in a vertical Bridgman furnace. The effects of changing the mold velocity from 5 to 110 mu m seconds(-1) on the macrosegregation of impurities during solidification were investigated. The macrostructures of the cylindrical Si ingots obtained in the experiments consist mostly of columnar grains parallel to the ingot axis. Because neither cells nor dendrites can be observed on ingot samples, the absence of precipitated particles and the fulfillment of the constitutional supercooling criterion suggest a planar solid-liquid interface for mold velocities a parts per thousand currency sign10 mu m seconds(-1). Concentration profiles of several impurities were measured along the ingots, showing that their bottom and middle are purer than the metallurgical Si from which they solidified. At the ingot top, however, impurities accumulated, indicating the typical normal macrosegregation. When the mold velocity decreases, the macrosegregation and ingot purity increase, changing abruptly for a velocity variation from 20 to 10 mu m seconds(-1). A mathematical model of solute transport during solidification shows that, for mold velocities a parts per thousand yen20 mu m seconds(-1), macrosegregation is caused mainly by diffusion in a stagnant liquid layer assumed at the solid-liquid interface, whereas for lower velocities, macrosegregation increases as a result of more intense convective solute transport. (AU)

• Processo FAPESP: 03/14118-1 - Refino do silicio por solidificacao direcional.
• Beneficiário: Joao Batista Ferreira Neto
• Modalidade de apoio: Auxílio à Pesquisa - Regular
• Processo FAPESP: 03/08576-7 - Modelagem matemática da solidificação de ligas binárias sob efeito de convecção natural no líquido e movimentação da fase sólida
• Beneficiário: Marcelo de Aquino Martorano
• Modalidade de apoio: Auxílio à Pesquisa - Jovens Pesquisadores