| Texto completo | |
| Autor(es): |
Aranda-Aguirre, Alejandro
;
Irikura, Kallyni
;
de Brito, Juliana Ferreira
;
Garcia-Segura, Sergi
;
Cerron-Calle, Gabriel A.
;
Zanoni, Maria Valnice Boldrin
;
Alarcon, Hugo
Número total de Autores: 7
|
| Tipo de documento: | Artigo Científico |
| Fonte: | JOURNAL OF ENERGY CHEMISTRY; v. 112, p. 12-pg., 2026-01-01. |
| Resumo | |
The use of Cu2O-based photocathodes has demonstrated the promising activity of these earth-abundant materials for the photoelectrochemical CO2 reduction reaction (CO2RR), particularly in producing methanol. However, their application in long-term devices is hindered by severe photocorrosion. To address this limitation, photocathode designs incorporating Schottky barriers, heterojunctions, and scaffolding layers have been explored. In this work, a CuBi2O4/CuO thin layer was employed as a scaffold to support Cu2O films with either seeded or grown morphologies for enhanced photoelectrochemical CO2RR. Photoelectrochemical testing in CO2-saturated electrolyte revealed that 0.55 V vs. reversible hydrogen electrode (RHE) yielded the highest activity and stability for methanol (CH3OH) production, outperforming more negative potentials. Furthermore, the present work highlighted that electrolyte engineering can be used to promote the generation of alternative products such as methyl acetate (CH3COOCH3). The presence of CuBi2O4/CuO scaffold was critical for allowing this pathway, providing both enhanced stability and improved charge transfer on the Cu2O surface. The generation of CH3COOCH3 is attributed to locally modified microenvironments that facilitate the esterification reaction when acetate is present in solution. These findings highlight the role of scaffold engineering in improving photocathode performance and electrolyte tuning in steering product selectivity toward scarcely explored, added-value compounds such as methyl acetate. (c) 2025 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights are reserved, including those for text and data mining, AI training, and similar technologies. (AU) | |
| Processo FAPESP: | 23/10027-5 - Redução de espécies como H+, CO2 e N2 para geração de energia concomitantemente a oxidação de contaminantes orgânicos |
| Beneficiário: | Juliana Ferreira de Brito |
| Modalidade de apoio: | Auxílio à Pesquisa - Projeto Inicial |
| Processo FAPESP: | 14/50945-4 - INCT 2014: Instituto Nacional de Tecnologias Alternativas para Detecção, Avaliação Toxicológica e Remoção de Micropoluentes e Radioativos |
| Beneficiário: | Maria Valnice Boldrin |
| Modalidade de apoio: | Auxílio à Pesquisa - Temático |