| Texto completo | |
| Autor(es): Mostrar menos - |
Soares-Paulino, Antonio A.
;
Giroldo, Lilian
;
Celante, Gizele
;
Oliveira, Elisabete
;
Santos, Sergio M.
;
Mendes, Ricardo F.
;
Paz, Filipe A. Almeida
;
Fioroto, Alexandre M.
;
Oliveira, Pedro, V
;
Serrano, Silvia H. P.
;
Lodeiro, Carlos
;
Dos Santos, Alcindo A.
Número total de Autores: 12
|
| Tipo de documento: | Artigo Científico |
| Fonte: | DYES AND PIGMENTS; v. 160, p. 9-pg., 2019-01-01. |
| Resumo | |
A new fluorescent probe based on Tellurium-Rhodamine (TR) was designed, synthetized and fully characterized by H-1 NMR, C-13 NMR, Te-125 NMR, HRMS, IR and single crystal X-ray diffraction. A mechanism of Hg2+ detection, based on the oxidation of tellurium by Hg2+ was observed and fully understood. The new monomer chemosensor TR shows a high fluorescent quantum yield Phi = 0.41, excellent selectivity and good sensibility towards Hg2+, with a limit of detection of 2.95 mu mol/L. (AU) | |
| Processo FAPESP: | 16/09579-0 - Síntese de Selenetos e Teluretos Orgânicos para Detecção e Intercepção de Entidades Oxidantes Endógenas |
| Beneficiário: | Alcindo Aparecido dos Santos |
| Modalidade de apoio: | Auxílio à Pesquisa - Regular |