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High strength and low elastic modulus α/β cp-Ti/Ti-33Nb-33Zr multilayered in-situ heterostructure produced by accumulative roll bonding

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Autor(es):
Afonso, Conrado Ramos Moreira ; Lourenco, Mariana Luna ; Pacheco, Gabriel Yoshika Ramos ; Minarik, Peter ; Vesely, Jozef ; Magalhaes, Danielle Cristina Camilo
Número total de Autores: 6
Tipo de documento: Artigo Científico
Fonte: JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T; v. 40, p. 13-pg., 2026-01-01.
Resumo

Developing and improving new alloys, primarily Ti-based systems, have been investigated to replace, repair, or reconstruct lost or damaged tissues while balancing relative cost, mechanical properties, corrosion resistance, and biological response. In this context, the main objective of this study was to evaluate the feasibility of producing heterostructured materials (HM) by accumulative roll bonding (ARB) based on two Ti alloys: alpha-Ti (grade 2) and multi-principal element alloy (MEA) (3-Ti Ti-33Nb-33Zr (wt.%), with a combination of high strength and low elastic modulus for implant applications. The main results indicated that producing such heterostructured sheets with up to 7 ARB cycles at 500 degrees C is feasible. A continuous increase in hardness and a reduction in the elastic modulus were simultaneously observed with the increasing ARB cycles. In both cases, the rule-of-mixtures (considering 1:1 proportion) was not followed, resulting in higher-than-expected hardness and lower-than-expected elastic modulus. Microstructural characterization revealed significant grain refinement and a remarkable increase in dislocation density, which were identified as the primary drivers for the enhanced hardness. The reduction in elastic modulus was attributed to nanograined structure and interdiffusion at the interfaces, as confirmed by TEM analysis. The process successfully produced multilayered composite sheets with a high hardness of over 300 HV and a favorably reduced elastic modulus in the range of 65-89 GPa. Based on these findings, ARB is a very promising technique for producing Ti-based HM for biomedical purposes. (AU)

Processo FAPESP: 23/03242-7 - Obtenção de chapas heteroestruturadas de Cu/Nb com propriedades mecânicas e funcionais otimizadas
Beneficiário:Danielle Cristina Camilo Magalhães
Modalidade de apoio: Auxílio à Pesquisa - Regular
Processo FAPESP: 18/18293-8 - Ligas de titânio: transformações de fases e manufatura aditiva aplicadas na obtenção de materiais com gradientes funcionais
Beneficiário:Rubens Caram Junior
Modalidade de apoio: Auxílio à Pesquisa - Temático
Processo FAPESP: 24/12728-3 - Produção da Liga Beta Multiprincipal Ti-33Nb-33Zr através de Fusão a Arco, Manufatura Aditiva a Laser e Deformação Plástica Severa
Beneficiário:Mariana Luna Lourenço
Modalidade de apoio: Bolsas no Brasil - Programa Fixação de Jovens Doutores
Processo FAPESP: 21/03756-5 - Ligas avançadas de magnésio para aplicações de suporte de carga em Medicina
Beneficiário:Andrea Madeira Kliauga
Modalidade de apoio: Auxílio à Pesquisa - Regular
Processo FAPESP: 23/16836-2 - Plataforma Multiusuário para obtenção de Pós através de Atomização Ultrasônica e Impressão 3D de Ligas de Titânio, multiprincipais e refratárias para Aplicações Biomédicas e Avançadas
Beneficiário:Conrado Ramos Moreira Afonso
Modalidade de apoio: Auxílio à Pesquisa - Programa Infraestrutura - Pequeno Médio Porte