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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Grain size effect on the structural and dielectric properties of Pb0.85La0.15TiO3 ferroelectric ceramic compound

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Autor(es):
Mesquita, Alexandre [1, 2, 3] ; Basso Bernardi, Maria Ines [2] ; Godart, Claude [1, 3] ; Pizani, Paulo Sergio [4] ; Michalowicz, Alain [1, 3] ; Mastelaro, Valmor Roberto [2]
Número total de Autores: 6
Afiliação do(s) autor(es):
[1] CNRS, Inst Chim & Mat Paris Est, F-94320 Thiais - France
[2] Univ Sao Paulo, IFSC, Sao Carlos, SP - Brazil
[3] Univ Paris Est, F-94320 Thiais - France
[4] Univ Fed Sao Carlos, Dept Fis, BR-13560 Sao Carlos, SP - Brazil
Número total de Afiliações: 4
Tipo de documento: Artigo Científico
Fonte: CERAMICS INTERNATIONAL; v. 38, n. 7, p. 5879-5887, SEP 2012.
Citações Web of Science: 9
Assunto(s):Materiais ferroelétricos   Espectroscopia Raman   Difração por raios X
Resumo

This paper presents a study of the influence of particle size on the structural and dielectric properties of Pb0.85La0.15TiO3 (PLT15) ferroelectric ceramic samples. The samples were prepared with average grain size of 1.69 +/- 0.08 mu m and 146 +/- 8 nm using, respectively, conventional and spark plasma sintering techniques. A decrease in the tetragonality degree as the crystallite size decreased was explained by an internal stress caused by the existence of a large amount of grain boundaries. The local structure exhibited no significant modification and the dielectric measurements showed a diffuse phase transition and a reduction in the permittivity magnitude at T-m as the average grain size decreased. The nanostructured ceramic sample prepared at a relatively lower temperature and sintering time presented a dielectric constant value of approximately 2000 at room temperature. (c) 2012 Elsevier Ltd and Techna Group S.r.l. All rights reserved. (AU)

Processo FAPESP: 07/00011-1 - Síntese e caracterização estrutural de compostos ferroelétricos relaxores Pb1-xRxZr0,40Ti0,60O3 (R = La, BA)
Beneficiário:Alexandre Mesquita
Modalidade de apoio: Bolsas no Brasil - Doutorado