Dispersive liquid-liquid microextraction combined with laser-induced breakdown spectrometry and inductively coupled plasma optical emission spectrometry to elemental analysis

Autor(es)

Gaubeur, I. ^[1] ; Aguirre, M. A. ^{[2, 3]} ; Kovachev, N. ^{[2, 3]} ; Hidalgo, M. ^{[2, 3]} ; Canals, A. ^{[2, 3]}

Afiliação do(s) autor(es)

^[1] Fed Univ ABC, Human & Nat Sci Ctr, BR-09210971 Santo Andre, SP - Brazil

^[2] Univ Alicante, Dept Analyt Chem & Food Sci, E-03080 Alicante - Spain

^[3] Univ Alicante, Univ Mat Inst, E-03080 Alicante - Spain

• Tipo de documento: Artigo Científico
• Fonte: Microchemical Journal; v. 121, p. 219-226, JUL 2015.
• Citações Web of Science: 19

Resumo

In this paper, two analytical methodologies based on the combination of dispersive liquid-liquid microextraction with inductively coupled plasma optical emission spectrometry and laser-induced breakdown spectrometry, respectively, were evaluated for simultaneous preconcentration and detection of Cd, Co, Ni, Pb and Zn. The microextraction procedure was based on the injection of appropriate quantities of 1-undecanol and methanol into the sample solution containing the complexes formed between metal ions and 1-(2-pyridylazo) 2-naphtol (PAN). The main experimental factors affecting the complexation and the extraction of metals (pH, PAN concentration, salt addition and extractant solvent and disperser solvent volume) were optimized using a multivariate analysis consisting of two steps: a Plackett-Burman design followed by a Circumscribed Central Composite Design (CCCD). Under optimum microextraction conditions, the analytical features of the proposed methodologies were assessed. Accuracy was evaluated by analyzing two certified reference materials, yielding results in agreement with the certified values. Both methodologies were applied to the analysis of a number of beverage samples. (C) 2015 Elsevier B.V. All rights reserved. (AU)

• Processo FAPESP: 11/19730-3 - Emprego da extração em ponto nuvem (CPE) e da microextração líquido-líquido dispersiva (DLLME) no desenvolvimento de métodos analíticos para a pré-concentração e determinação espectrométrica de metais
• Beneficiário: Ivanise Gaubeur
• Modalidade de apoio: Auxílio à Pesquisa - Regular