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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Effect of the synthesis method on the properties and catalytic activities of Au/Pd nanoparticles supported on organophilic clay

Texto completo
Autor(es):
Teixeira-Neto, A. A. [1, 2] ; Faceto, B. [2] ; Siebra, L. S. [2] ; Teixeira-Neto, E. [1]
Número total de Autores: 4
Afiliação do(s) autor(es):
[1] Brazilian Ctr Res Energy & Mat, Brazilian Nanotechnol Natl Lab, BR-13085903 Campinas, SP - Brazil
[2] Fed Univ ABC, Ctr Nat & Human Sci, BR-09210580 Santo Andre, SP - Brazil
Número total de Afiliações: 2
Tipo de documento: Artigo Científico
Fonte: APPLIED CLAY SCIENCE; v. 116, p. 175-181, NOV 2015.
Citações Web of Science: 3
Resumo

Au and Pd mono and bimetallic nanoparticles supported on organoclay were prepared using two different approaches. In the first method (POST), the intercalated surfactant molecules were used as capturing and stabilizing agents of metal cations to prepare metal nanoparticles. In the second method (PRE), pre-made surfactant-stabilized metal nanoparticles were directly incorporated in the cationic clay. The structure and composition of the materials were probed by XRD, ICP-AES, XPS, CHN, TGA, and UV-Vis spectroscopy, while morphology was characterized by SEM. It was revealed that by the POST method, the particles remained majoritarily on the outer surface of the clay, while by the PRE method, the particles were intercalated. The materials were tested on the oxidation of benzyl alcohol, and the results showed that monometallic catalysts synthesized by the PRE method were more active. For the bimetallic materials, the activity was higher for the POST material, which was composed of AuPd alloy nanoparticles, while the PRE material was composed of isolated Au and Pd nanoparticles. (C) 2015 Elsevier B.V. All rights reserved. (AU)

Processo FAPESP: 11/12521-0 - Catalisadores de oxidação baseados em nanopartículas metálicas suportadas em sílica mesoporosa
Beneficiário:Ângela Albuquerque Teixeira Neto
Linha de fomento: Auxílio à Pesquisa - Regular
Processo FAPESP: 13/11298-0 - Morfologia e morfogênese de catalisadores heterogêneos bimetálicos com arquiteturas planejadas
Beneficiário:Érico Teixeira Neto
Linha de fomento: Auxílio à Pesquisa - Regular