Evaluation of electrical properties of glass-ceramics obtained from mill scale

Autor(es)

Montedo, O. R. K. ^[1] ; Alves, I. T. ^[1] ; Faller, C. A. ^[1] ; Bertan, F. M. ^[2] ; Pive, D. H. ^[3] ; Piva, R. H. ^[3]

Afiliação do(s) autor(es)

^[1] Univ Extrema Catarinense UNESC, Grp Pesquisa CERTEC, BR-88806000 Criciuma, SC - Brazil

^[2] Colorminas Colorificio & Mineracao, BR-88820000 Icara, SC - Brazil

^[3] Univ Fed Sao Carlos, Programa Posgrad Ciencia & Engn Mat, PPGCEM, BR-13565905 Sao Carlos, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Materials Research Bulletin; v. 72, p. 90-97, DEC 2015.
• Citações Web of Science: 7

Resumo

The inertization of hazardous chemical elements has been shown to be an efficient way to achieve the waste valorization (e.g., mill scale) generated during the steel production process. Vitrification is an inertization technique which is used to obtain glass-ceramic materials with notable characteristics, such as electrical properties. In this context, this study aims to evaluate electrical characteristics of glass-ceramic materials produced from mill scale by means of impedance spectroscopy. Six compositions were prepared by melting and powder technology in order to obtain glass-ceramics. Electrochemical impedance spectroscopy measurements showed that the electrical conductivity of the glass-ceramics was strongly dependent on the structural modifications, particularly when these affect the Na+ charge carrier. Crystallization reduced the electrical conductivity due to the physical hindrance of the Na+ ions with the addition of ZrO2. Moreover, higher resistivity values for these glass-ceramics (up to 2.5 x 10(4) Omega m) were obtained at temperatures below 950 degrees C when the electrical conductivity was as low as 10(-10) S m(-1). At 300 degrees C, a values ranged from 41 to 104. The relative ease with which the electrical properties can be changed makes these glass-ceramics potential low cost materials for application as glass semiconductors in thermal insulation or as LTCCs for microelectronic devices. (C) 2015 Elsevier Ltd. All rights reserved. (AU)

• Processo FAPESP: 13/14189-8 - Revestimentos de zircônia codopada com Nb2O5/Ta2O5 + Sc2O3 como barreira térmica para aplicação em turbinas
• Beneficiário: Roger Honorato Piva
• Modalidade de apoio: Bolsas no Brasil - Doutorado