| Texto completo | |
| Autor(es): |
de Oliveira, Regiane Cristina
[1]
;
Assis, Marcelo
[1]
;
Teixeira, Mayara Mondego
[1]
;
Penha da Silva, Maya Dayana
[1]
;
Li, Maximo Siu
[2]
;
Andres, Juan
[3]
;
Gracia, Lourdes
[3]
;
Longo, Elson
[4]
Número total de Autores: 8
|
| Afiliação do(s) autor(es): | [1] Univ Fed Sao Carlos, CDMF UFSCar, POB 676, BR-13565905 Sao Carlos, SP - Brazil
[2] Univ Sao Paulo, IFSC, POB 369, BR-13560970 Sao Carlos, SP - Brazil
[3] Univ Jaume 1, Dept Quim Fis & Analit, Castellon de La Plana 12071 - Spain
[4] Univ Estadual Paulista, CDMF UNESP, POB 355, BR-14801907 Araraquara, SP - Brazil
Número total de Afiliações: 4
|
| Tipo de documento: | Artigo Científico |
| Fonte: | Journal of Physical Chemistry C; v. 120, n. 22, p. 12254-12264, JUN 9 2016. |
| Citações Web of Science: | 15 |
| Resumo | |
This article aims to gather together in one place and for first time the formation process of Ag nanoparticles (NPs) on beta-AgVO3 crystals, driven by an accelerated electron beam from an electronic microscope under high vacuum. Synthesis and optical properties of beta-AgVO3 are reported, and the relationship between structural disorder and photoluminescence emissions is discussed. First principle calculations, within a QTAIM framework, have been carried out to provide a deeper insight and understanding of the observed nucleation and early evolution of Ag nanoparticles (NPs) on beta-AgVO3 crystals. The Ag nucleation and formation is a result of structural and electronic changes of the {[}AgO5] and {[}AgO6] clusters, consistent with Ag metallic formation. (AU) | |
| Processo FAPESP: | 13/07296-2 - CDMF - Centro de Desenvolvimento de Materiais Funcionais |
| Beneficiário: | Elson Longo da Silva |
| Modalidade de apoio: | Auxílio à Pesquisa - Centros de Pesquisa, Inovação e Difusão - CEPIDs |