Evaluation of standard dilution analysis (SDA) of beverages and foodstuffs by ICP OES

Autor(es)

Virgilio, Alex ^[1] ; Schiavo, Daniela ^[2] ; Nobrega, Joaquim A. ^[1] ; Donati, George L. ^[3]

Afiliação do(s) autor(es)

^[1] Univ Fed Sao Carlos, Dept Chem, Grp Appl Instrumental Anal, POB 676, BR-13565905 Sao Carlos, SP - Brazil

^[2] Agilent Technol Brazil, BR-06460040 Barueri, SP - Brazil

^[3] Wake Forest Univ, Dept Chem, Salem Hall, Box 7486, Winston Salem, NC 27109 - USA

• Tipo de documento: Artigo Científico
• Fonte: Journal of Analytical Atomic Spectrometry; v. 31, n. 6, p. 1216-1222, JUN 2016.
• Citações Web of Science: 10

Resumo

A procedure is described using the novel standard dilution analysis (SDA) calibration method for the determination of As, Cd, Cr, Cu, Fe, Mn, Pb, Se and Zn in drinks and foodstuffs by Synchronous Vertical Dual View (SVDV) ICP OES. SDA parameters such as standards concentrations, dilution ratio, signal plateau duration and internal standard element and concentrations were evaluated to improve accuracy, precision and sensitivity. Liquid sweetener, soy sauce, vinegar, grape juice, coconut water, red wine, cachaga (Brazilian sugarcane spirit), beer, energy drink, isotonic and soft drink were analyzed after a 10 fold dilution with 1% v/v HNO3. Spiked samples were analyzed to check the method's accuracy. Recoveries were in the 89-111% range, with precisions better than 4.7%. Results were also compared with values obtained with the traditional calibration methods of external calibration, internal standardization and standard additions. Limits of detection for SDA were in the 3-20 mu g L-1 range, which are slightly higher than those obtained using external calibration (0.3-9 mu g L-1). Arsenic, Cd and Pb were not found in the samples evaluated. Concentrations determined for the other analytes were in the following ranges: 174 +/- 23 mu g L-1 Cr, 843 +/- 41 mu g L-1 Cu, 266-+/- 3903 mu g L-1 Fe, 1420-6700 mu g L-1 Mn, 300-1790 mu g L-1 Se, and 1030-14 520 mu g L-1 Zn. The SDA-ICP OES method is a simpler and faster alternative to perform matrix-matching with adequate accuracy and precision. (AU)

• Processo FAPESP: 14/18393-1 - Avaliação da análise em fluxo por gradiente como estratégia de calibração para técnicas espectroanalíticas com fonte de plasma
• Beneficiário: Alex Virgilio
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado