Zirconia on Reduced Graphene Oxide Sheets: Synergistic Catalyst with High Selectivity for H2O2 Electrogeneration

Autor(es)

Carneiro, Jussara F. ; Paulo, Maria J. ; Siaj, Mohamed ; Tavares, Ana C. ; Lanza, Marcos R. V.

• Tipo de documento: Artigo Científico
• Fonte: CHEMELECTROCHEM; v. 4, n. 3, p. 508-513, MAR 2017.
• Citações Web of Science: 1

Resumo

In situ electrogeneration of hydrogen peroxide through the oxygen reduction reaction (ORR) represents a potentially greener route for wastewater treatment. However, the development of adequate catalysts following a two-electron pathway with high selectivity and low overpotential is still of great importance. To address this issue, nanoparticles of zirconium oxide supported on reduced graphene oxide (rGO) sheets were prepared through a hydrothermal reaction, and the composite catalysts were tested for the ORR in both acid and alkaline media. The presence of zirconium oxides (ZrO2-x and ZrO2) significantly improved the activity of rGO for the ORR and its selectivity toward H2O2 electrogeneration. Indeed, an increase from 73.7 to 89.5% was obtained in acid solution, and from 72.9 to 83.1% in alkaline medium. The high activity of the composite catalysts is assigned to the synergistic effect between ZrO2-x and rGO. The highest selectivity for H2O2 electrogeneration was correlated to the presence of ZrO2 phase. In addition, the zirconia-rGO catalysts are stable and reusable. Therefore, these composites are very promising catalysts to be used in gas diffusion electrodes for advanced oxidation processes. (AU)

• Processo FAPESP: 16/01937-4 - Síntese de óxidos binários de metais (Nb, Zr, Ta, Ru, Mo e Co) suportados em carbono amorfo para a produção de eletrodos de difusão gasosa (EDG) para a eletrossíntese de H2O2 in situ em reatores de fluxo.
• Beneficiário: Marcos Roberto de Vasconcelos Lanza
• Modalidade de apoio: Auxílio à Pesquisa - Regular
• Processo FAPESP: 11/14314-1 - Estudo da modificação de eletrodos de difusão gasosa com catalisadores redox para a eletrogeração de peróxido de hidrogênio (H2O2) in situ
• Beneficiário: Marcos Roberto de Vasconcelos Lanza
• Modalidade de apoio: Auxílio à Pesquisa - Regular