| Texto completo | |
| Autor(es): |
Monteiro, Emily V.
;
Varela, Hamilton
;
Faria, Roberto B.
Número total de Autores: 3
|
| Tipo de documento: | Artigo Científico |
| Fonte: | Chemical Physics Letters; v. 684, p. 219-224, SEP 16 2017. |
| Citações Web of Science: | 1 |
| Resumo | |
The simultaneous influence of temperature and flow rate (k(0)) in the oscillatory regime of the bromate-oxalic acid-acetone-Ce(III) oscillating reaction was investigated. The influence of temperature was evaluated in terms of the oscillatory activation energy (E-omega), which was determined at different flow rates. Increasing k(0), the oscillatory activation energy is decreased, tending to a limit value, E-omega infinity. The sensitivity of E-omega, with k(0) is described by the parameter eta = dE omega/d(1/k(0)). E-omega infinity and eta are global properties of any particular oscillating reaction and describes a correlation between the dynamical behavior and temperature, and should be used when comparing different oscillating reactions. (C) 2017 Elsevier B.V. All rights reserved. (AU) | |
| Processo FAPESP: | 13/16930-7 - Eletrocatálise V: processos eletrocatalíticos de interconversão entre as energias química e elétrica |
| Beneficiário: | Edson Antonio Ticianelli |
| Modalidade de apoio: | Auxílio à Pesquisa - Temático |