Mechanical, rheological and degradation properties of PBAT nanocomposites reinforced by functionalized cellulose nanocrystals

Autor(es)

Pinheiro, I. F. ^[1] ; Ferreira, F. V. ^{[2, 1]} ; Souza, D. H. S. ^[3] ; Gouveia, R. F. ^[2] ; Lona, L. M. F. ^[1] ; Morales, A. R. ^[1] ; Mei, L. H. I. ^[1]

Afiliação do(s) autor(es)

^[1] Univ Estadual Campinas, Sch Chem Engn, UNICAMP, BR-13083970 Campinas, SP - Brazil

^[2] Brazilian Ctr Res Energy & Mat CNPEM, Brazilian Nanotechnol Natl Lab LNNano, Campinas, SP - Brazil

^[3] Univ Fed Rio de Janeiro, Inst Macromol Prof Eloisa Mano IMA, Rio de Janeiro, RJ - Brazil

• Tipo de documento: Artigo Científico
• Fonte: EUROPEAN POLYMER JOURNAL; v. 97, p. 356-365, DEC 2017.
• Citações Web of Science: 34

Resumo

In this study, the effects of cellulose nanocrystals modified with octadecyl isocyanate on rheological, mechanical and degradation properties of nanocomposites based on poly (butylene adipate-co-terephthalate) (PBAT) were reported. Nanocomposites were prepared by melt mixing procedure of PBAT with 3, 5 and 7 wt% cellulose nanocrystals. The increase of PBAT-based nanocomposites mechanical Strength was discussed as a function of the cellulose nanocrystals surface chemistry, and the optimal amount of nanofillers in the nanocomposites, whereas the biodegradation rate of the polymer was related to the cellulose nanocrystals hydrophobicity. The study here presented promotes further understanding of cellulose nanocrystals functiOnalliation and its effect on the overall properties of polymeric nanocomposites. (AU)

• Processo FAPESP: 16/09588-9 - Funcionalização de nanocristais de celulose para o desenvolvimento de nanocompósitos biodegradáveis PBAT/CNC
• Beneficiário: Filipe Vargas Ferreira
• Modalidade de apoio: Bolsas no Brasil - Doutorado