Ethanol dehydrogenative reactions catalyzed by copper supported on porous Al-Mg mixed oxides

Autor(es)

Petrolini, Davi D. ^[1] ; Cassinelli, Wellington H. ^[2] ; Pereira, Cristiane A. ^[3] ; Urquieta-Gonzalez, Ernesto A. ^[3] ; Santilli, Celso V. ^[1] ; Martins, Leandro ^[1]

Afiliação do(s) autor(es)

^[1] Univ Estadual Paulista, UNESP, Inst Quim, R Prof Francisco Degni 55, BR-14800900 Araraquara, SP - Brazil

^[2] Inst Fed Sao Paulo Campus Avare, Av Prof Celso Ferreira da Silva 1333, BR-18707150 Avare, SP - Brazil

^[3] Univ Fed Sao Carlos, Ctr Pesquisas Mat Avancados & Energia, Rodovia Washington Luis, Km 235, BR-13565905 Sao Carlos, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: RSC ADVANCES; v. 9, n. 6, p. 3294-3302, JAN 24 2019.
• Citações Web of Science: 0

Resumo

Mixed aluminum and magnesium oxides (AlMgO) prepared by means of an emulsion-mediated sol-gel method was impregnated with copper nitrate solution and used in the ethanol dehydrogenative reactions to produce acetaldehyde and ethyl acetate. The emulsified system allowed to obtain a macro-mesoporous support that resulted in an outstanding dispersion of copper. The porous catalyst was about 3 times more active than the non-porous counterpart, due to the formation on the support's surface of Cu-0 together with the more active Cu+ species. In fact, the simultaneous presence of Cu+ and Cu-0 were advantageous for the catalytic performance, as the turnover frequencies, were 122 and 166 h(-1) for the non-porous reference catalyst and for the porous one, respectively. Both catalysts deactivated due to copper particles sintering, however the porous one deactivated less, as a consequence of the better dispersion of the Cu species on the macro and mesoporous support. Acetaldehyde was the main product, however by increasing the contact time by 6.6 times, the conversion of ethanol on the nonporous catalyst reached about 90% with a selectivity to ethyl acetate of 20% by means of the coupling reaction of ethanol and acetaldehyde. The selectivity to ethyl acetate was favoured on an increased support/copper interface that is given by larger copper particles. (AU)

• Processo FAPESP: 15/05321-5 - Síntese de catalisadores com poros estruturados derivados da hidrotalcita por uso combinado de química sol-gel, tensoativos e emulsão
• Beneficiário: Davi Domingos Petrolini
• Modalidade de apoio: Bolsas no Brasil - Doutorado
• Processo FAPESP: 13/01328-0 - Metodologias avançadas de síntese de zeólitas hierárquicas e caracterização por diferentes técnicas para melhor utilização de materiais microporosos em catálise heterogênea
• Beneficiário: Leandro Pierroni Martins
• Modalidade de apoio: Auxílio à Pesquisa - Regular