Annealing control of hydrothermally grown hematite nanorods: Implication of structural changes and Cl concentration on weak ferromagnetism

Autor(es)

Carvalho-Jr, W. M. ; Mendonca-Ferreira, L. ^[1] ; Costa, F. N. ^[1] ; Ferreira, F. F. ^[1] ; Muche, D. N. F. ^{[2, 3]} ; Tofanello, R. A. ^[1] ; Castro, R. H. R. ^{[2, 3]} ; Souza, F. L. ^{[2, 3, 1]}

Afiliação do(s) autor(es)

^[1] Carvalho-Jr, Jr., W. M., Univ Fed Abc, CCNH, BR-09210170 Santo Andre, SP - Brazil

^[2] Univ Calif Davis, Dept Mat Sci & Engn, One Shields Ave, Davis, CA 95616 - USA

^[3] Univ Calif Davis, NEAT ORU, One Shields Ave, Davis, CA 95616 - USA

• Tipo de documento: Artigo Científico
• Fonte: Journal of Alloys and Compounds; v. 799, p. 83-88, AUG 30 2019.
• Citações Web of Science: 0

Resumo

In-situ X-ray diffraction coupled with thermogravimetry and differential scanning calorimetry were used to elucidate the crystal phase transition from akaganeite to hematite nanorods. The results indicate that though complete phase transformation occurs at similar to 663 K, residual chlorines from the hydrothermal synthesis conditions strongly affect spin moment. The high temperature (>1023 K) shock-annealing reduced the chlorine concentration and consequent suppress most of surface defects on the rods. High temperature annealed hematite nanorods were then studied in terms of magnetic properties under different applied hydrostatic pressures and exhibited a shift of T-M to higher values, from 261 to 282 K with initial rate (partial derivative T-M/partial derivative P coefficient) of 46 K GPa(-1). Such positive dependence of T-M with hydrostatic applied pressure is consistent with several works reported in the literature investigating different morphologies in bulk and at nanoscale. In fact, gradual reduction of Cl species increases the spin mobility allowing the appearance of weak-ferromagnetism at room temperature. The crossover results strongly support the hypothesis that Cl dominates spin mobility. (C) 2019 Elsevier B.V. All rights reserved. (AU)

• Processo FAPESP: 16/02157-2 - Estudo da superfície de nanoestruturas de hematita pela técnica de micro-calorimetria de adsorção de água
• Beneficiário: Flavio Leandro de Souza
• Modalidade de apoio: Bolsas no Exterior - Pesquisa
• Processo FAPESP: 13/05471-1 - Efeito de dopantes em nanoestruturas semicondutoras e seu impacto no desempenho fotocatalítico
• Beneficiário: Waldemir Moura de Carvalho Junior
• Modalidade de apoio: Bolsas no Brasil - Doutorado
• Processo FAPESP: 13/07296-2 - CDMF - Centro de Desenvolvimento de Materiais Funcionais
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• Modalidade de apoio: Auxílio à Pesquisa - Centros de Pesquisa, Inovação e Difusão - CEPIDs
• Processo FAPESP: 11/19924-2 - Estudo e desenvolvimento de novos materiais avançados: eletrônicos, magnéticos e nanoestruturados: uma abordagem interdisciplinar
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• Modalidade de apoio: Auxílio à Pesquisa - Temático