Performance of the MCM-41-NH2 Functionalized Mesoporous Material Synthetized from the Rice Husk Ash on the Removal of the Polycyclic Aromatic Hydrocarbons

Autor(es)

Costa, Jose A. S. ^{[1, 2]} ; Sarmento, Victor H. V. ^[3] ; Romao, Luciane P. C. ^[4] ; Paranhos, Caio M. ^[2]

Afiliação do(s) autor(es)

^[1] Univ Aveiro, Dept Chem, CICECO, P-3810193 Aveiro - Portugal

^[2] Univ Fed Sao Carlos, Dept Chem, Polymer Lab, BR-13565905 Sao Carlos, SP - Brazil

^[3] Univ Fed Sergipe, Dept Chem, BR-49100000 Itabaiana, Sergipe - Brazil

^[4] Univ Fed Sergipe, Dept Chem, BR-49100000 Sao Cristovao, Sergipe - Brazil

• Tipo de documento: Artigo Científico
• Fonte: SILICON; v. 12, n. 8 NOV 2019.
• Citações Web of Science: 2

Resumo

In this work, the authors propose of the synthesis of a new adsorbent functionalized mesoporous material (MCM-41-NH2 (RHA)) from the Brazilian rice husk for the removal of the polycyclic aromatic hydrocarbons (PAHs). The new MCM-41-NH2 (RHA) was characterized using FTIR, TGA, SAXS, and N-2 adsorption-desorption analyses, on the other hand, the removal experiments were performed to determine the adsorption parameters, such as the initial concentration, MCM-41-NH2 (RHA) amount, pH, time, and temperature. The hydrothermal/post-grafting methods were sustainable for the synthesis of the MCM-41-NH2 (RHA) functionalized mesoporous material, the same presented the main characteristic absorption bands of the mesoporous arrays, hexagonal mesostructure, type IV isotherms with H1 hysteresis, high surface area, and good thermal stability. Assessment of the adsorption of the MCM-41-NH2 (RHA) showed that the amount of the PAHs mixture adsorbed increased with the increase of the initial concentration, MCM-41-NH2 (RHA) amount, and contact time, as well as, the pH = 5.6 was the best for the removal of the PAHs mixture. However, the temperature variation did not significantly alter the efficiency of the MCM-41-NH2 (RHA). The removal percentage of the PAHs were 81.20, 94.25, 94.87, and 98.14% for the naphthalene (Nap), benzo{[}a]pyrene (B{[}a]P), benzo{[}k]fluoranthene (B{[}k]F), and benzo{[}b]fluoranthene (B{[}b]F), respectively, with the equilibrium time of approximately 200 min for the all PAHs. In addition, the adsorption equilibrium followed the nonlinear pseudo-second-order and the Langmuir models, which describe satisfactory adsorption of the PAHs mixture on the MCM-41-NH2 (RHA) functionalized mesoporous material. (AU)

• Processo FAPESP: 18/18894-1 - Síntese de materiais mesoporosos bioativos para utilização em biomedicina regenerativa
• Beneficiário: José Arnaldo Santana Costa
• Modalidade de apoio: Bolsas no Exterior - Estágio de Pesquisa - Pós-Doutorado
• Processo FAPESP: 14/05679-4 - Desenvolvimento de materiais mesoporosos baseados em sílica oriunda de biomassa para utilização como sistema remediador de hidrocarbonetos policíclicos aromáticos (HPAs)
• Beneficiário: José Arnaldo Santana Costa
• Modalidade de apoio: Bolsas no Brasil - Doutorado
• Processo FAPESP: 17/06775-5 - Desenvolvimento de membranas poliméricas híbridas tunáveis na remediação de hidrocarbonetos policíclicos aromáticos (HPAs) oriundos do petróleo
• Beneficiário: José Arnaldo Santana Costa
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado
• Processo FAPESP: 13/07296-2 - CDMF - Centro de Desenvolvimento de Materiais Funcionais
• Beneficiário: Elson Longo da Silva
• Modalidade de apoio: Auxílio à Pesquisa - Centros de Pesquisa, Inovação e Difusão - CEPIDs