Busca avançada
Ano de início
Entree
(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Novel zero-dimensional lead-free bismuth based perovskites: from synthesis to structural and optoelectronic characterization

Texto completo
Autor(es):
Ozorio, Mailde S. [1] ; Oliveira, Willian X. C. [2] ; Silveira, Julian F. R. V. [1] ; Nogueira, Ana Flavia [3] ; Da Silva, Juarez L. F. [1]
Número total de Autores: 5
Afiliação do(s) autor(es):
[1] Univ Sao Paulo, Sao Carlos Inst Chem, POB 780, BR-13560970 Sao Carlos, SP - Brazil
[2] Univ Fed Minas Gerais, Inst Cincias Exatas, Dept Qum, POB 6154, BR-13083970 Belo Horizonte, MG - Brazil
[3] Univ Estadual Campinas, Inst Chem, POB 6154, BR-13083970 Campinas, SP - Brazil
Número total de Afiliações: 3
Tipo de documento: Artigo Científico
Fonte: MATERIALS ADVANCES; v. 1, n. 9, p. 3439-3448, DEC 1 2020.
Citações Web of Science: 1
Resumo

Despite high photo-conversion efficiency, the short long-term stability and toxicity issues have prevented lead-based perovskites from becoming the standard in high efficiency solar cells. Hence, lead-free perovskites with low inorganic framework dimensionality have attracted great attention because of their optoelectronic properties and superior stability. In this work, we present a combined experimental and theoretical investigation of the structural and optoelectronic properties of three novel highly stable zero-dimensional perovskites (discrete connectivity of the inorganic framework), where fused octahedra {[}BixIy](z-) are interspersed by large organic cations: H(2)bpy(2+) for 1, Hdmphen(+) for 2 and the combination of H(2)terpy(+2) and Hterpy(+) for 3 (bpy = 4,4-bipyridine, dmphen = 2,9-dimethyl-1,10-phenanthroline, terpy = 2,2 ` ;6 ` ,2 ` ` -terpyridine). In each of these compounds, the inorganic moieties display different morphologies, either edge-sharing bi-octahedra (Bi2I104-, 1), face-sharing bi-octahedra (Bi2I93-, 2) or isolated octahedra (BiI63-, 3). The consistent results of experimental and theoretical characterization reveal that distortions in the coordination octahedra are most prominent as the number of shared iodide species increases. The experimental optical response presents similar trends between all three materials, which is dominated by transitions inside the octahedron, while the transitions between cations and anionic bismuth-iodide clusters displayed very low intensity at a lower photon energy, an aspect that was described qualitatively well by theoretical characterization. Overall, these materials show different potential prospects, such as application in hybrid dimensional materials, acting as dielectrics for instance, or as a source of Bi for the synthesis of other lead-free perovskites. (AU)

Processo FAPESP: 18/21401-7 - EMU concedido no processo 2017/11631-2: cluster computacional de alto desempenho - ENIAC
Beneficiário:Juarez Lopes Ferreira da Silva
Modalidade de apoio: Auxílio à Pesquisa - Programa Equipamentos Multiusuários
Processo FAPESP: 17/11631-2 - CINE: desenvolvimento computacional de materiais utilizando simulações atomísticas, meso-escala, multi-física e inteligência artificial para aplicações energéticas
Beneficiário:Juarez Lopes Ferreira da Silva
Modalidade de apoio: Auxílio à Pesquisa - Programa Centros de Pesquisa em Engenharia
Processo FAPESP: 17/11986-5 - Geração e Armazenamento de Novas Energias: trazendo desenvolvimento tecnológico para o país
Beneficiário:Ana Flávia Nogueira
Modalidade de apoio: Auxílio à Pesquisa - Programa Centros de Pesquisa em Engenharia