The Elusive Structure of Magadiite, Solved by 3D Electron Diffraction and Model Building

Autor(es):Mostrar menos -

Krysiak, Yasar ^{[1, 2]} ; Maslyk, Marcel ^[1] ; Silva, Bruna Nadia ^[3] ; Plana-Ruiz, Sergi ^{[4, 5]} ; Moura, Hipassia M. ^[6] ; Munsignatti, Erica O. ^[6] ; Vaiss, Viviane S. ^[3] ; Kolb, Ute ^{[1, 4]} ; Tremel, Wolfgang ^[1] ; Palatinus, Lukas ^[2] ; Leitao, Alexandre Amaral ^[3] ; Marler, Bernd ^[7] ; Pastore, Heloise O. ^[6]

Afiliação do(s) autor(es)

^[1] Johannes Gutenberg Univ Mainz, Inst Inorgan Chem & Analyt Chem, D-55128 Mainz - Germany

^[2] Czech Acad Sci, Inst Phys, Dept Struct Anal, CZ-17000 Prague - Czech Republic

^[3] Univ Fed Juiz de Fora, Dept Chem, Grp Phys Chem Solids & Interfaces, BR-36036900 Juiz De Fora, MG - Brazil

^[4] Tech Univ Darmstadt, Dept Mat & Geosci, D-64287 Darmstadt - Germany

^[5] Univ Barcelona, LENS, MIND IN2UB, Elect Sect, Engineer Dept, Barcelona 08028 - Spain

^[6] Univ Estadual Campinas, Inst Chem, Micro & Mesoporous Mol Sieves Grp, BR-13083970 Campinas, SP - Brazil

^[7] Ruhr Univ Bochum, Dept Geol Mineral & Geophys, D-44801 Bochum - Germany

• Tipo de documento: Artigo Científico
• Fonte: CHEMISTRY OF MATERIALS; v. 33, n. 9, p. 3207-3219, MAY 11 2021.
• Citações Web of Science: 1

Resumo

In addition to a great swelling ability, layered silicates also allow the functionalization of their interlayer region to form various robust green materials that are used as CO2 adsorbents, drug carriers, or catalysts. Here, the unique magadiite structure, which has resisted elucidation despite many attempts and applications the material offers, is finally described. A material-specific strategy allowed the use of 3D electron diffraction which led to the success of deciphering the atomic structure. In order to enable an ab initio structure solution of the electron beam sensitive material, a sodium-free dehydrated form of magadiite was synthetically isolated, and, from that, it was subsequently possible to derive a structure model for the sodium form of magadiite, later successfully refined against powder X-ray diffraction data. Furthermore, a geometry optimization and simulations of spectroscopic data with DFT methods confirm the obtained crystal structure of sodium magadiite. These results finally prompted a detailed description of the layers and of the chemically active interlayer region and provide a huge impact toward the design of new and more efficient materials based on functionalized magadiite and related structures. (AU)

• Processo FAPESP: 14/06942-0 - Sólidos lamelares nanoestruturados como catalisadores ácidos, básicos e redox
• Beneficiário: Heloise de Oliveira Pastore
• Modalidade de apoio: Auxílio à Pesquisa - Temático