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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Dual magnetic field and temperature optical probes of controlled crystalline phases in lanthanide-doped multi-shell nanoparticles

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Autor(es):
Ferreira, Flavia de Sousa [1] ; de Morais, Amanda Justino [1] ; Santos Calado, Claudia Manuela [1] ; Iikawa, Fernando [2] ; Couto Junior, Odilon D. D. [2] ; Brunet, Gabriel [3] ; Murugesu, Muralee [3] ; Mazali, Italo O. [1] ; Sigoli, Fernando A. [1]
Número total de Autores: 9
Afiliação do(s) autor(es):
[1] Univ Estadual Campinas, Inst Chem, UNICAMP, POB 6154, BR-13083970 Campinas, SP - Brazil
[2] Univ Estadual Campinas, Inst Phys Gleb Wataghin, UNICAMP, POB 6165, BR-13083970 Campinas, SP - Brazil
[3] Univ Ottawa, Dept Chem & Biomol Sci, Ottawa, ON K1N 6N5 - Canada
Número total de Afiliações: 3
Tipo de documento: Artigo Científico
Fonte: NANOSCALE; v. 13, n. 35 JUL 2021.
Citações Web of Science: 0
Resumo

The engineering of core@multi-shell nanoparticles containing heterogeneous crystalline phases in different layers constitutes an important strategy for obtaining optical probes. The possibility of obtaining an opto-magnetic core@multi-shell nanoparticle capable of emitting in the visible and near-infrared ranges by upconversion and downshifting processes is highly desirable, especially when its optical responses are dependent on temperature and magnetic field variations. This work proposes the synthesis of hierarchically structured core@multi-shell nanoparticles of heterogeneous crystalline phases: a cubic core containing Dy-III ions responsible for magnetic properties and optically active hexagonal shells, where Er-III, Yb-III, and Nd-III ions were distributed. This system shows at least three excitation energies located at different biological windows, and its emission intensities are sensitive to temperature and external magnetic field variations. The selected crystalline phases of the core@multi-shell nanoparticles obtained in this work is fundamental to the development of multifunctional materials with potential applications as temperature and magnetic field optical probes. (AU)

Processo FAPESP: 12/11382-9 - Modulação ótica de sistemas nanoestruturados usando ondas acústicas de superfícies
Beneficiário:Odilon Divino Damasceno Couto Júnior
Modalidade de apoio: Auxílio à Pesquisa - Jovens Pesquisadores
Processo FAPESP: 13/22127-2 - Desenvolvimento de novos materiais estratégicos para dispositivos analíticos integrados
Beneficiário:Lauro Tatsuo Kubota
Modalidade de apoio: Auxílio à Pesquisa - Temático