Small difference between the nonlinear refractions of normal and deuterated solvents measurable by nonlinear ellipse rotation

Autor(es)

Fernandes, J. C. ^[1] ; Barbano, E. C. ^[2] ; Siqueira, J. P. ^[3] ; Misoguti, L. ^[1]

Afiliação do(s) autor(es)

^[1] Univ Sao Paulo, Sao Carlos Inst Phys, POB 369, BR-13560970 Sao Carlos, SP - Brazil

^[2] Univ Fed Parana, Dept Fis, POB 19044, BR-81531980 Curitiba, Parana - Brazil

^[3] Univ Estadual Campinas, Inst Fis Gleb Wataghin, BR-13083859 Campinas, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS; v. 38, n. 9, p. 2663-2668, SEP 1 2021.
• Citações Web of Science: 0

Resumo

In this work, we have measured the nonlinear refractions of six different normal and deuterated solvents: water, DMSO, methanol, acetone, toluene, and chloroform using a nonlinear ellipse rotation (NER) signal with femtosecond laser pulses. High-precision, self-referenced NER measurements could detect small differences between the refractive nonlinearities of normal and deuterated solvents. We observed that the replacement of hydrogen with deuterium atoms slightly reduces the magnitude of the nonlinearity. Basically, the reduction is related to the amount of hydrogen and the replacement by deuterium atoms in the molecules; in this way, toluene (chloroform) presents the major (minor) difference. By measuring the nonlinear refraction as a function of the pulse width, we also could observe that the refractive nonlinearity increases as the pulse gets longer. Using a simple empirical model, we could discriminate the ultrafast electronic and delayed orientational refractive nonlinearities of these six pairs of solvents. (C) 2021 Optical Society of America (AU)

• Processo FAPESP: 18/11283-7 - Fotônica não linear: espectroscopia e processamento avançado de materiais
• Beneficiário: Cleber Renato Mendonça
• Modalidade de apoio: Auxílio à Pesquisa - Temático
• Processo FAPESP: 19/00638-1 - Estudo das não linearidades de semicondutores policristalinos de estrutura blenda de zinco: dependências espectral e espacial
• Beneficiário: Lino Misoguti
• Modalidade de apoio: Auxílio à Pesquisa - Regular