A versatile filler in polyhydroxyalcanoates filaments for FDM: A diverse panorama for pullulan application

Autor(es)

Martins, Larissa S. ^[1] ; Cortat, Lucas I. C. C. O. ^[2] ; Zanini, Noelle C. ^[3] ; Barbosa, Rennan F. S. ^[3] ; Souza, Alana G. ^[3] ; Medeiros, Simone F. ^[4] ; Rosa, Derval S. ^[3] ; Mulinari, Daniella R. ^[2]

Afiliação do(s) autor(es)

^[1] State Univ Rio de Janeiro UERJ, Dept Chem & Environm, BR-27537000 Resende - Brazil

^[2] State Univ Rio de Janeiro UERJ, Dept Mechan & Energy, BR-27537000 Resende - Brazil

^[3] Fed Univ ABC UFABC, Ctr Engn Modeling & Appl Social Sci CECS, Santo Andre, SP - Brazil

^[4] Univ Sao Paulo, Engn Sch Lorena, Chem Engn Dept, BR-12602810 Lorena, SP - Brazil

• Tipo de documento: Artigo Científico
• Fonte: MATERIALS TODAY COMMUNICATIONS; v. 28, SEP 2021.
• Citações Web of Science: 1

Resumo

Continuous advances in 3D printing technology, associated with the development of sustainable materials, have driven the manufacture of new biofilaments compatible with numerous applications, such as automotive, robotics, food, and biomedical. In this work, sustainable filaments of PHB and PHBV filled with 5 wt% of pullulan were prepared, and its chemical, thermal, and morphological properties, crystallinity, 3D printing capability, and cytotoxicity were evaluated. Two PHBV samples were compared with different valerate concentrations: 6 and 8 wt%. Raman and FTIR results indicated that pullulan altered the polymeric chain organization, impacting the polymer crystallinity as corroborated by DSC analysis. The composites showed higher heat resistance in the range of 5-30% of mass loss, and all samples showed adequate thermal stability for fused deposition modeling (FDM) processing. pullulan increased the PHB and PHBVs crystallinity due to the nucleation effect and shifted melting temperatures to lower temperatures due to the dispersed phase/matrix interface. While PHB composites showed an irregular surface with large agglomerates, PHBVs composites showed good dispersion and filler/matrix interaction, which slightly impacted the filaments diameters, but classified these materials as a potential for 3D filaments printing. PHBV filaments were printed into biomedical scaffolds, and the results indicated the influence of valerate and filler dispersion, in which 8 wt% valerate is the adequate concentration for 3D printing. The printed scaffolds represent a novel biocomposite to the tissue regeneration field, confirmed by the cell viability values above 80%, being appropriate for biomedical and other 3D printing applications. (AU)

• Processo FAPESP: 18/11277-7 - Filmes de PBAT com nanoestruturas de celulose tratadas com óleos essenciais encapsulados para embalagens ativas
• Beneficiário: Derval dos Santos Rosa
• Modalidade de apoio: Auxílio à Pesquisa - Regular