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Hybrid MAPbI3 Perovskite Growth Mechanism from Irregular Particles to Cuboid and Hopper-Type Morphologies

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Autor(es):
Bonadio, Ariany ; Souza, Jose A.
Número total de Autores: 2
Tipo de documento: Artigo Científico
Fonte: Journal of the Brazilian Chemical Society; v. N/A, p. 8-pg., 2022-03-30.
Resumo

Methylammonium lead iodide (MAPbI3), used as light-harvesting layer in solar cell devices, has attracted great attention from scientific community due to its excellent photovoltaic performance. In this work, we have shown a comprehensive study on the hybrid organic-inorganic MAPbI3 perovskite growth mechanism from irregular small particles to cuboid shape followed by hoppertype morphology through a systematically change on both the temperature and lead source concentration during the solution synthesis process. Indeed, we have observed very interesting hopper growth resulting in a pyramid-hollow like morphology. We have explained the morphology evolution by taking into account thermodynamics growth, which compete with kinetics growth under nonequilibrium conditions. (AU)

Processo FAPESP: 18/15682-3 - Síntese e caracterização das propriedades físicas de materiais semicondutores micro/nano estruturados
Beneficiário:José Antonio Souza
Modalidade de apoio: Auxílio à Pesquisa - Regular
Processo FAPESP: 18/14181-0 - Síntese, caracterização e simulação computacional de perovskitas APbX3 (a = CS e CH3NH3; X = i, Cl e Br) híbridas
Beneficiário:Ariany Bonadio
Modalidade de apoio: Bolsas no Brasil - Doutorado Direto