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Promising Tb3+-doped gallium tungsten-phosphate glass scintillator: Spectroscopy, energy transfer and UV/X-ray sensing

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Autor(es):
Lodi, Thiago A. ; dos Santos, Jessica F. M. ; Galleani, Gustavo ; Jacobsohn, Luiz G. ; Catunda, Tomaz ; de Camargo, Andrea S. S.
Número total de Autores: 6
Tipo de documento: Artigo Científico
Fonte: Journal of Alloys and Compounds; v. 904, p. 10-pg., 2022-05-25.
Resumo

Undoped and Tb3+-doped (0.5-10 mol%) gallium tungsten-phosphate glasses, in the new compositional system NaPO3-Ga2O3-Na2WO4, were prepared and characterized by UV-visible absorption, photoluminescence excitation and emission, excited state decay measurements and X-ray excited radioluminescence measurements. A detailed study of ion-ion energy transfer, based on the analysis of decay curves by the Inokuti-Hirayama model, indicated that the energy transfer process affecting the emitting level 5D3 of Tb3+ is related to dipole-dipole interaction. Additionally, a theoretical model was successfully employed to establish a correlation between the emission color variation due to changes in the green to blue emission ratio (IG/IB). The emission spectra of the undoped and Tb3+-doped glasses were measured under UV and X-ray excitation. From the viewpoint of UV-sensing, samples doped with up to 7.0 mol% Tb3+ do not present visible emission quenching, whereas X-ray sensing is not prone to quenching at all up to 10 mol% Tb3+ doping. These characteristics, associated to a relatively high density, highlight the potential of these glasses as X-ray scintillators. (C) 2022 Elsevier B.V. All rights reserved. (AU)

Processo FAPESP: 13/07793-6 - CEPIV - Centro de Ensino, Pesquisa e Inovação em Vidros
Beneficiário:Edgar Dutra Zanotto
Modalidade de apoio: Auxílio à Pesquisa - Centros de Pesquisa, Inovação e Difusão - CEPIDs
Processo FAPESP: 18/03931-9 - Preparação de vidros e vitrocerâmicas de fluorofosfatos dopados com íons terras-raras para potencial uso como detectores de radiação.
Beneficiário:Gustavo Galleani
Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado