Molecular interactions of (ionic liquid butylammonium methanoate plus alcohols) at several temperatures. Part II: sec-Butylammonium methanoate (S4Met)

Autor(es)

Hoga, Heloisa Emi ; Fernandes, Robert Lunkez ; Olivieri, Gustavo Vieira ; Torres, Ricardo Belchior

• Tipo de documento: Artigo Científico
• Fonte: JOURNAL OF CHEMICAL THERMODYNAMICS; v. 178, p. 16-pg., 2022-12-08.

Resumo

Volumetric and acoustic properties were obtained by density (rho) and speed of sound (u) experimental values for the binary liquid systems containing the protic ionic liquid (IL) sec-butylammonium methanoate (S4Met) + alcohols (ethanol, 1-propanol, 1-butanol and 1-pentanol) over the whole composition range at different temperatures (293.15-313.15) K and ambient pressure (p = 92.3 kPa). A neutralization reaction was carried out under controlled temperature to synthesize S4Met, which underwent spectroscopic analyses to guarantee its formation. All the excess properties, namely excess molar volume, VEm, excess partial molar volumes,VEi , and deviation in isentropic compressibility,Delta kappa S, presented negative values. Other volumetric properties such as partial molar volumes,Vi, apparent molar volumes, V phi i and infinite dilution volumes,Vi infinity, were determined. In addition to the thermodynamic approach, spectroscopy techniques essentially 1H NMR, 13C NMR, FTIR were useful in order to elucidate intermolecular interactions among the species in solutions. Lastly, the Peng-Robinson-Stryjek-Vera equation of state (PRSV EOS) was used to correlate the excess molar volumes. (AU)

• Processo FAPESP: 09/14556-5 - Propriedades volumétricas, de transportes e acústicas de sistemas binários contendo líquidos iônicos: estudo experimental e modelagem
• Beneficiário: Ricardo Belchior Tôrres
• Modalidade de apoio: Auxílio à Pesquisa - Regular
• Processo FAPESP: 16/02652-3 - Estudo experimental e modelagem de propriedades termodinâmicas de sistemas binários contendo {dimetil carbonato (DMC) + álcoois} a altas pressões
• Beneficiário: Gustavo Vieira Olivieri
• Modalidade de apoio: Bolsas no Brasil - Mestrado
• Processo FAPESP: 19/00289-7 - Estudo da reação de epoxidação do óleo de soja: modelagem cinética e estudo do processo em reator contínuo
• Beneficiário: Gustavo Vieira Olivieri
• Modalidade de apoio: Bolsas no Brasil - Doutorado