Electrical Conductivity Boost: In Situ Polypyrrole Polymerization in Monolithically Integrated Surface-Supported Metal-Organic Framework Templates

Autor(es)

Vello, Tatiana Parra ; Albano, Luiz Gustavo Simao ; dos Santos, Thamiris Cescon ; Colletti, Julia Cantovitz ; Santos Batista, Carlos Vinicius ; Leme, Vitoria Fernandes Cintra ; dos Santos, Thamiris Costa ; Miguel, Maria Paula Dias Carneiro ; de Camargo, Davi Henrique Starnini ; Bof Bufon, Carlos Cesar

• Tipo de documento: Artigo Científico
• Fonte: SMALL; v. N/A, p. 14-pg., 2023-09-26.

Resumo

Recent progress in synthesizing and integrating surface-supported metal-organic frameworks (SURMOFs) has highlighted their potential in developing hybrid electronic devices with exceptional mechanical flexibility, film processability, and cost-effectiveness. However, the low electrical conductivity of SURMOFs has limited their use in devices. To address this, researchers have utilized the porosity of SURMOFs to enhance electrical conductivity by incorporating conductive materials. This study introduces a method to improve the electrical conductivity of HKUST-1 templates by in situ polymerization of conductive polypyrrole (PPy) chains within the SURMOF pores (named as PPy@HKUST-1). Nanomembrane-origami technology is employed for integration, allowing a rolled-up metallic nanomembrane to contact the HKUST-1 films without causing damage. After a 24 h loading period, the electrical conductivity at room temperature reaches approximately 5.10-6 S m-1. The nanomembrane-based contact enables reliable electrical characterization even at low temperatures. Key parameters of PPy@HKUST-1 films, such as trap barrier height, dielectric constant, and tunneling barrier height, are determined using established conduction mechanisms. These findings represent a significant advancement in real-time control of SURMOF conductivity, opening pathways for innovative electronic-optoelectronic device development. This study demonstrates the potential of SURMOFs to revolutionize hybrid electronic devices by enhancing electrical conductivity through intelligent integration strategies. A significant enhancement in electrical conductivity and a comprehensive electrical characterization at low temperatures of surface-supported metal-organic frameworks (SURMOFs) are detailed in this study. By employing in situ polymerization of polypyrrole (PPy), this work successfully integrates an HKUST-1 SURMOF thin-film into a solid-state device using an innovative nanomembrane-origami technology concept. This integration allows for damage-free and self-adjusting contact. The electrical characterization conducted at low temperatures exhibits remarkable consistency with well-established electrical conduction mechanisms. Most notably, the achieved electrical conductivity reaches an impressive value of 5.10-6 S m-1, representing a remarkable improvement of seven orders of magnitude when compared to the initial pristine film. This groundbreaking outcome underscores the substantial potential of this approach in enhancing the electrical properties of SURMOFs, paving the way for exciting prospects in the development of advanced hybrid electronic devices.image (AU)

• Processo FAPESP: 17/02317-2 - Interfaces em materiais: propriedades eletrônicas, magnéticas, estruturais e de transporte
• Beneficiário: Adalberto Fazzio
• Modalidade de apoio: Auxílio à Pesquisa - Temático
• Processo FAPESP: 14/50906-9 - INCT 2014: em Materiais Complexos Funcionais (INOMAT)
• Beneficiário: Fernando Galembeck
• Modalidade de apoio: Auxílio à Pesquisa - Temático
• Processo FAPESP: 16/25346-5 - Dispositivos capacitivos para caracterização de nanoestruturas híbridas: estudo das propriedades elétricas de estruturas metal-orgânicas de superfície -SURMOFs- e ftalocianinas metálicas
• Beneficiário: Tatiana Parra Vello
• Modalidade de apoio: Bolsas no Brasil - Doutorado
• Processo FAPESP: 19/01561-2 - Estudos de mecanismos de crescimentos de estruturas metal-orgânicas montadas em superfície para aplicação em dispositivos elétricos
• Beneficiário: Tatiana Parra Vello
• Modalidade de apoio: Bolsas no Exterior - Estágio de Pesquisa - Doutorado
• Processo FAPESP: 14/25979-2 - Fabricação e caracterização de dispositivos e sistemas baseados em nanomembranas híbridas
• Beneficiário: Carlos César Bof Bufon
• Modalidade de apoio: Auxílio à Pesquisa - Jovens Pesquisadores
• Processo FAPESP: 17/25553-3 - Fabricação e caracterização de nanomembranas de estruturas metal-orgânicas de superfície (SURMOFs) auto-enroladas para aplicações em dispositivos eletrônicos ultracompactos
• Beneficiário: Luíz Gustavo Simão Albano
• Modalidade de apoio: Bolsas no Brasil - Pós-Doutorado