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Determination of soil pore size distribution and water retention curve by internal magnetic field modulation at low field 1H NMR

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Autor(es):
Novotny, Etelvino Henrique ; deAzevedo, Eduardo Ribeiro ; de Godoy, Gustavo ; Consalter, Daniel Martelozo ; Cooper, Miguel
Número total de Autores: 5
Tipo de documento: Artigo Científico
Fonte: Geoderma; v. 431, p. 15-pg., 2023-02-09.
Resumo

The determination of the soil pore size distribution, water retention curve, and derived parameters that control important processes in soils, such as water supply for plants; infiltration; water and solute movement in soils; erosion; plant nutrients and contaminants transport, etc, are challenging and the available methods are expen-sive, time-consuming and prone to bias and errors. The use of 1H Nuclear Magnetic Resonance (NMR) relax-ometry to characterise the soil porosity and hydraulic properties through spin-lattice and spin-spin relaxometry results in an ill-posed problem with two correlated unknown quantities: the pore length scales, and surface relaxivity. To overcome this limitation of NMR relaxometry, we propose the use of a method that directly ac-cesses the NMR diffusion modes governed only by the pore size, and therefore, independent of the unknown surface relaxivity. The manuscript describes an unprecedent application in Soil Science of the Decay due to Diffusion in Internal Field (DDIF) method to successfully determine the pore size distribution of undisturbed soil samples, as well as to estimate the water retention curves from the pore size distribution. (AU)

Processo FAPESP: 09/18354-8 - Dinâmica e estrutura de sistemas poliméricos estudados por ressonância magnética nuclear
Beneficiário:Eduardo Ribeiro de Azevedo
Modalidade de apoio: Auxílio à Pesquisa - Regular
Processo FAPESP: 17/24465-3 - Métodos de RMN para caracterização de paredes celulares de plantas: desenvolvimento e aplicações para tecnologias de biocombustíveis de segunda geração
Beneficiário:Eduardo Ribeiro de Azevedo
Modalidade de apoio: Auxílio à Pesquisa - Programa BIOEN - Regular