| Texto completo | |
| Autor(es): |
Alkathy, Mahmoud S.
;
Eiras, J. A.
;
Zabotto, Fabio L.
;
Raju, K. C. James
Número total de Autores: 4
|
| Tipo de documento: | Artigo Científico |
| Fonte: | JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS; v. 32, n. 10, p. 13-pg., 2020-07-10. |
| Resumo | |
Narrowing the bandgap energy of perovskite ferroelectrics is a potential task for improving PV applications. This study examined the effect of Ni2+/Na(+)co-substitution on the structural, optical, electrical, and magnetic properties of Ba1-x(Ni-x/2,Na-x)TiO3(BTNaNi-x) ceramics, where (0 <= x <= 0.08), prepared by solid-state reaction method. X-ray diffraction along with structure refinement verifies the existence of perovskite structure with a tetragonal phase in all samples. The morphological study reveals a non-uniform grain size distribution with a decrease in grain size with an increase in co-substitution concentration. XPS study gives direct evidence of oxygen vacancies in the investigated sample. The oxygen vacancies and octahedral distortion accompanying the Ni2+/Na(+)co-substitution significantly reduce the optical bandgap of BaTiO(3)ceramics from 3.14 to 2.688 eV. The temperature dependence of the dielectric constant is measured in the range of 30-250 degrees C at the frequency of 1 kHz. The results reveal that the transition temperature gradually decreased with an increase in Ni(2+)and Na(+)concentrations. This phenomenon was interpreted based on reducing grain size and tetragonality with co-substitution. The ferroelectric and magnetic properties are determined by (P-E) and (M-H) hysteresis loops at room temperature.Magnetic properties are significantly enhanced with an increase in the Ni2+, Na(+)contents in the system. The correlation between the ESR width parameter (Delta H) and asymmetry parameter (Pays) with concentrations (x) reveals that the sample withx = 0.08 has a strong magnetic nature compared to other samples. (AU) | |
| Processo FAPESP: | 19/03110-8 - Síntese e caracterização fotovoltaica de filmes finos à base de perovskitas ferroelétricas e multiferróicas para aplicação em células solares |
| Beneficiário: | Mahmoud Saleh Mohammed Alkathy |
| Modalidade de apoio: | Bolsas no Brasil - Pós-Doutorado |