Recyclable Palladium Catalyst Supported on Dolomite for Dynamic Kinetic Resolution of (+/-)-1-Phenylethylamine

Autor(es)

Mendonca, Renata C. Z. ; Esteves, Laura M. ; Oliveira, Hugo A. ; de Lima, Sania M. ; de Siqueira, Fernanda A.

• Tipo de documento: Artigo Científico
• Fonte: CATALYSIS LETTERS; v. 152, n. 4, p. 10-pg., 2021-07-01.

Resumo

This work proposes a new selective palladium catalyst supported on dolomite to synthesize enantiomerically enriched N-[(R)-( +)-1-phenylethyl] amide. 2.5 wt.% Pd catalyst demonstrated high activity for reactions performed under mild conditions reaching a total enantiomeric excess up to 99%. It could be reused up to 5 cycles after the regeneration step. [GRAPHICS] . (AU)

• Processo FAPESP: 19/00641-2 - Estudos sobre a Resolução cinética dinâmica quimioenzimática de álcoois e aminas, visando à síntese de moléculas enantiomericamente puras, com potencial atividade biológica.
• Beneficiário: Fernanda Amaral de Siqueira
• Modalidade de apoio: Auxílio à Pesquisa - Regular