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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Conjugated copolymers based on poly(fluorenylene vinylene) derivatives containing push-pull units: Synthesis and characterization

Texto completo
Autor(es):
de Freitas, Jilian N. [1] ; Li, Rosamaria W. C. [2] ; Nogueira, Ana Flavia [1] ; Gruber, Jonas [2]
Número total de Autores: 4
Afiliação do(s) autor(es):
[1] Univ Estadual Campinas UNICAMP, Inst Quim, BR-13084397 Campinas, SP - Brazil
[2] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo - Brazil
Número total de Afiliações: 2
Tipo de documento: Artigo Científico
Fonte: Materials Chemistry and Physics; v. 130, n. 1-2, p. 223-230, OCT 17 2011.
Citações Web of Science: 3
Resumo

In this work we present the synthesis, via the Gilch route, of two polymers: poly(9,9-dioctyl-2,7-fluorenylene vinylene) and poly(2-bromo-5-hexyloxy-1,4-phenylene vinylene), which contain fluorene and push-pull (2-bromo-5-hexyloxy-1,4-phenylene) units, respectively. We also present the synthesis of novel copolymers based on the combination of these materials in different proportions. Using the Gilch route, the synthesis yields varied between 42% and 71%, and the average molar masses varied between 4 x 10(3) g mol(-1) and 70 x 10(3) g mol(-1). The thermal, electrochemical and photophysical properties of these polymers were investigated, and their application as hole transporting materials in organic solar cells, in combination with a fullerene derivative (electron transport material), is also presented. (C) 2011 Elsevier B.V. All rights reserved. (AU)

Processo FAPESP: 05/56924-0 - Células fotovoltaicas híbridas de polímeros condutores e nanopartículas inorgânicas
Beneficiário:Jilian Nei de Freitas
Linha de fomento: Bolsas no Brasil - Doutorado