Conjugated copolymers based on poly(fluorenylene vinylene) derivatives containing push-pull units: Synthesis and characterization

Autor(es)

de Freitas, Jilian N. ^[1] ; Li, Rosamaria W. C. ^[2] ; Nogueira, Ana Flavia ^[1] ; Gruber, Jonas ^[2]

Afiliação do(s) autor(es)

^[1] Univ Estadual Campinas UNICAMP, Inst Quim, BR-13084397 Campinas, SP - Brazil

^[2] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Materials Chemistry and Physics; v. 130, n. 1-2, p. 223-230, OCT 17 2011.
• Citações Web of Science: 3

Resumo

In this work we present the synthesis, via the Gilch route, of two polymers: poly(9,9-dioctyl-2,7-fluorenylene vinylene) and poly(2-bromo-5-hexyloxy-1,4-phenylene vinylene), which contain fluorene and push-pull (2-bromo-5-hexyloxy-1,4-phenylene) units, respectively. We also present the synthesis of novel copolymers based on the combination of these materials in different proportions. Using the Gilch route, the synthesis yields varied between 42% and 71%, and the average molar masses varied between 4 x 10(3) g mol(-1) and 70 x 10(3) g mol(-1). The thermal, electrochemical and photophysical properties of these polymers were investigated, and their application as hole transporting materials in organic solar cells, in combination with a fullerene derivative (electron transport material), is also presented. (C) 2011 Elsevier B.V. All rights reserved. (AU)

• Processo FAPESP: 05/56924-0 - Celulas fotovoltaicas hibridas de polimeros condutores e nanoparticulas inorganicas.
• Beneficiário: Jilian Nei de Freitas
• Modalidade de apoio: Bolsas no Brasil - Doutorado