| Texto completo | |
| Autor(es): |
Costa, Elizama R.
;
Andrade, Floyd C. D.
;
de Albuquerque, Danilo Yano
;
Ferreira, Luanne E. M.
;
Lima, Thiago M.
;
Lima, Carolina G. S.
;
Silva, Domingos S. A.
;
Urquieta-Gonzalez, Ernesto A.
;
Paixao, Marcio W.
;
Schwab, Ricardo S.
Número total de Autores: 10
|
| Tipo de documento: | Artigo Científico |
| Fonte: | NEW JOURNAL OF CHEMISTRY; v. 44, n. 35, p. 8-pg., 2020-09-21. |
| Resumo | |
Herein, we describe the preparation and thorough characterization of a novel magnetically recoverable copper(i)-exchanged beta-zeolite and its use as an efficient catalyst for the synthesis of 1,2,3-triazolesviathe one-pot three-component reaction of organic halides, terminal acetylenes, and sodium azide in water. The magnetically recoverable beta-zeolite could be easily separated from the reaction mixture with the aid of a magnet and reused in several consecutive reactions. Importantly, a series of characterizations studies allowed us to disclose the mechanism for the deactivation of the catalyst, and therefore to propose a method for its reactivation. (AU) | |
| Processo FAPESP: | 14/50249-8 - Green chemistry: sustainable synthetic methods employing benign solvents, safer reagents, and bio-renewable feedstock |
| Beneficiário: | Arlene Gonçalves Corrêa |
| Modalidade de apoio: | Auxílio à Pesquisa - Programa Centros de Pesquisa Aplicada |
| Processo FAPESP: | 13/06558-3 - Catálise metálica assimétrica: preparação de alcoóis quirais e seus derivados a partir de reagentes orgânicos de zinco poli-funcionalizados e aplicação de novos ligantes quirais suportados em nanopartículas magnéticas |
| Beneficiário: | Ricardo Samuel Schwab |
| Modalidade de apoio: | Auxílio à Pesquisa - Regular |