| Texto completo | |
| Autor(es): |
Santos, Camila S.
;
Soares, Caio C. S. P.
;
Vieira, Adriano S.
;
Burtoloso, Antonio C. B.
Número total de Autores: 4
|
| Tipo de documento: | Artigo Científico |
| Fonte: | GREEN CHEMISTRY; v. 21, n. 23, p. 10-pg., 2019-12-07. |
| Resumo | |
A novel and direct method for the production of polyols with long chains is developed under simple and mild conditions starting from renewable gamma-valerolactone (GVL), a chemical platform easily obtained from biomass. The key step involves a Claisen condensation between two GVL molecules to provide a cyclic hemiketal in 85% yield. After alkylation and/or reduction, this ketal serves as a new platform to produce several high-value-added branched chain molecules with carbons ranging from C10 to C21. (AU) | |
| Processo FAPESP: | 17/23329-9 - Síntese de ciclopentanos substituídos e polióis de cadeia longa a partir de plataformas químicas abundantes e oriundas da biomassa |
| Beneficiário: | Antonio Carlos Bender Burtoloso |
| Modalidade de apoio: | Auxílio à Pesquisa - Regular |